267 0

Nanofibers synthesis of ND:PANI composite by liquid/liquid interfacial polymerization and study on the effect of NDs on growth mechanism of nanofibers

Title
Nanofibers synthesis of ND:PANI composite by liquid/liquid interfacial polymerization and study on the effect of NDs on growth mechanism of nanofibers
Author
VANISH KUMAR
Keywords
Interfacial polymerization; Polyaniline; Nanodiamonds; Mechanism; Composite
Issue Date
2016-07
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Citation
EUROPEAN POLYMER JOURNAL, v. 83, Page. 1-9
Abstract
Polyaniline (PANI) has exclusive doping/dedoping chemistry and it can be produced in various oxidation states with different electrical and structural properties. The nanocomposite of PANI with nanodiamonds shows unique properties due to molecular level interaction between nanodiamond (ND) and PANI structures. We synthesized ND:PANI composite first time by interfacial polymerization under controlled conditions. The composites were characterized with the help of UV-vis, FTIR, Raman spectroscopies and field effect scanning electron microscope. Herein, we are reporting synthesis of fibrous and conducting composites. In addition, varying concentrations of NDs improves primary growth, lowers the diameter of fibers and cause augmentation in the polymerization. The detailed mechanism of PANI and ND:PANI synthesis is validated with the time dependent study of the aqueous phase. The whole mechanism is alienated into six zones on the basis of reaction progression. (C) 2016 Elsevier Ltd. All rights reserved.
URI
https://www.sciencedirect.com/science/article/pii/S0014305716304153?via%3Dihubhttps://repository.hanyang.ac.kr/handle/20.500.11754/74291
ISSN
0014-3057; 1873-1945
DOI
10.1016/j.eurpolymj.2016.07.025
Appears in Collections:
COLLEGE OF ENGINEERING[S](공과대학) > CIVIL AND ENVIRONMENTAL ENGINEERING(건설환경공학과) > Articles
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE