110 0

Pd-Catalyzed Sequential C-C Bond Formation and Cleavage: Evidence for an Unexpected Generation of Arylpalladium(II) Species

Title
Pd-Catalyzed Sequential C-C Bond Formation and Cleavage: Evidence for an Unexpected Generation of Arylpalladium(II) Species
Author
윤소원
Issue Date
2012-07
Publisher
Amer Chemical SOC
Citation
Journal of the American Chemical Society, 2012, 134(28), P.11308-11311
Abstract
A Pd(II)-catalyzed reaction engaging alkenyl beta-keto esters is reported that leads to the formation of 1-naphthols and an unexpected generation of arylpalladium-(II) species. Interception of the in situ generated arylpalladium(II) species in a Mizoroki-Heck reaction, together with additional mechanistic studies, provided strong evidence in support of the first aromatization-driven beta-carbon elimination process. A single Pd catalyst served to promote a series of both C-C bond forming and cleavage events in an unprecedented manner.
URI
https://pubs.acs.org/doi/10.1021/ja304616qhttps://repository.hanyang.ac.kr/handle/20.500.11754/73033
ISSN
0002-7863
DOI
10.1021/ja304616q
Appears in Collections:
COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE