Pd-Catalyzed Sequential C-C Bond Formation and Cleavage: Evidence for an Unexpected Generation of Arylpalladium(II) Species
- Title
- Pd-Catalyzed Sequential C-C Bond Formation and Cleavage: Evidence for an Unexpected Generation of Arylpalladium(II) Species
- Author
- 윤소원
- Issue Date
- 2012-07
- Publisher
- Amer Chemical SOC
- Citation
- Journal of the American Chemical Society, 2012, 134(28), P.11308-11311
- Abstract
- A Pd(II)-catalyzed reaction engaging alkenyl beta-keto esters is reported that leads to the formation of 1-naphthols and an unexpected generation of arylpalladium-(II) species. Interception of the in situ generated arylpalladium(II) species in a Mizoroki-Heck reaction, together with additional mechanistic studies, provided strong evidence in support of the first aromatization-driven beta-carbon elimination process. A single Pd catalyst served to promote a series of both C-C bond forming and cleavage events in an unprecedented manner.
- URI
- https://pubs.acs.org/doi/10.1021/ja304616qhttps://repository.hanyang.ac.kr/handle/20.500.11754/73033
- ISSN
- 0002-7863
- DOI
- 10.1021/ja304616q
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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