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Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | 조은진 | - |
| dc.date.accessioned | 2018-07-25T08:09:50Z | - |
| dc.date.available | 2018-07-25T08:09:50Z | - |
| dc.date.issued | 2011-11 | - |
| dc.identifier.citation | Organic Letters, 2011, 13(24), P.6552-6555 | en_US |
| dc.identifier.issn | 1523-7060 | - |
| dc.identifier.issn | 1523-7052 | - |
| dc.identifier.uri | https://pubs.acs.org/doi/abs/10.1021/ol202885w | - |
| dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/72944 | - |
| dc.description.abstract | A method for the palladium-catalyzed trifluoromethylation of cyclohexenyl sulfonates has been developed. Various cyclohexenyl triflates and nonaflates underwent trifluoromethylation under mild reaction conditions using a catalyst system composed of Pd(dba)(2) or [(ally1)PdCl](2) and the monodentate biaryl phosphine ligand (t)BuXPhos. The trifluoromethyl anion (CF3-) or its equivalent for the process was generated in situ from TMSCF3 in combination with KF or TESCF3 in combination with RbF. | en_US |
| dc.description.sponsorship | We thank the National Institutes of Health (Grant GM46059) for financial support of this work. We thank Dr. Meredeth A. McGowan (Massachusetts Institute of Technology) and Dr. Andrew Parsons (Massachusetts Institute of Technology) for help with this manuscript. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | AMER Chemical SOC | en_US |
| dc.title | The Palladium-Catalyzed Trifluoromethylation of Vinyl Sulfonates | en_US |
| dc.type | Article | en_US |
| dc.relation.no | 24 | - |
| dc.relation.volume | 13 | - |
| dc.identifier.doi | 10.1021/ol202885w | - |
| dc.relation.page | 6552-6555 | - |
| dc.relation.journal | ORGANIC LETTERS | - |
| dc.contributor.googleauthor | Cho, Eun Jin | - |
| dc.contributor.googleauthor | Stephen L. Buchwald | - |
| dc.relation.code | 2011207322 | - |
| dc.sector.campus | S | - |
| dc.sector.daehak | GRADUATE SCHOOL[S] | - |
| dc.sector.department | DEPARTMENT OF BIONANOTECHNOLOGY | - |
| dc.identifier.pid | echo | - |
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