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Layer by layer assembly of ultrathin V2O5 anchored MWCNTs and graphene on textile fabrics for fabrication of high energy density flexible supercapacitor electrodes

Title
Layer by layer assembly of ultrathin V2O5 anchored MWCNTs and graphene on textile fabrics for fabrication of high energy density flexible supercapacitor electrodes
Author
배지현
Keywords
VANADIUM-OXIDE; HIGH-POWER; PERFORMANCE; CARBON; NANOWIRE; STORAGE; DEPOSITION; FILMS
Issue Date
2014-04
Publisher
ROYAL SOC CHEMISTRY
Citation
Nanoscale, 2014, 6(8), p.4125-4130
Abstract
Among transition metal oxides, vanadium oxides have received relatively modest attention for supercapacitor applications. Yet, this material is abundant, relatively inexpensive and offer several oxidation states which can provide a broad range of redox reactions suitable for supercapacitor operation. Electrochemical supercapacitors based on nanostructured vanadium oxide (V2O5) suffer from relatively low energy densities as they have low surface area and poor electrical conductivities. To overcome these problems, we developed a layer by layer assembly (LBL) technique in which a graphene layer was alternatively inserted between MWCNT films coated with ultrathin (3 nm) V2O5. The insertion of a conductive spacer of graphene between the MWCNT films coated with V2O5 not only prevents agglomeration between the MWCNT films but also substantially enhances the specific capacitance by 67%, to as high as similar to 2590 F g(-1). Furthermore, the LBL assembled multilayer supercapacitor electrodes exhibited an excellent cycling performance of >97%, capacitance retention over 5000 cycles and a high energy density of 96 W h kg(-1) at a power density of 800 W kg(-1). Our approach clearly offers an exciting opportunity for enhancing the device performance of metal oxide-based electrochemical supercapacitors suitable for next-generation flexible energy storage devices by employing a facile LBL assembly technique.
URI
http://pubs.rsc.org/en/Content/ArticleLanding/2014/NR/c3nr06820j#!divAbstracthttp://hdl.handle.net/20.500.11754/54099
ISSN
2040-3372; 2040-3364
DOI
10.1039/c3nr06820j
Appears in Collections:
COLLEGE OF HUMAN ECOLOGY[S](생활과학대학) > ETC
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