Palladium-catalyzed asymmetric hydrosilylation of styrenes with trichlorosilane
- Title
- Palladium-catalyzed asymmetric hydrosilylation of styrenes with trichlorosilane
- Author
- 한진욱
- Issue Date
- 2014-04
- Publisher
- Elsevier B.V
- Citation
- Tetrahedron: Asymmetry. Apr2014, Vol. 25 Issue 6/7, p479-484
- Abstract
- Asymmetric hydrosilylation of styrenes with trichlorosilane catalyzed by palladium complexes coordinated with chiral monodentate phosphorus ligands produces chiral benzylic silanes, which can be converted into enantiomerically enriched benzylic alcohols by a stereospecific oxidative cleavage of the carbonsilicon bond with retention of configuration. Due to its high catalytic activity and perfect regioselectivity without producing any by-products, it has recently become a potent methodology to prove the efficacy of newly-developed chiral ligands, especially monodentate ones, in asymmetric synthesis.
- URI
- https://www.sciencedirect.com/science/article/abs/pii/S0957416614000986http://hdl.handle.net/20.500.11754/50059
- ISSN
- 0957-4166
- DOI
- 10.1016/j.tetasy.2014.03.002
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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