Controlled Trifluoromethylation Reactions of Alkynes through Visible-Light Photoredox Catalysis
- Title
- Controlled Trifluoromethylation Reactions of Alkynes through Visible-Light Photoredox Catalysis
- Author
- 조은진
- Keywords
- iridium; radical reactions; ruthenium; trifluoromethylation; visible light
- Issue Date
- 2014-01
- Publisher
- WILEY-V C H VERLAG GMBH
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION; JAN 7 2014, 53, 2, p539-p542
- Abstract
- The control of a reaction that can form multiple products is a highly attractive and challenging concept in synthetic chemistry. A set of valuable CF3-containing molecules, namely trifluoromethylated alkenyl iodides, alkenes, and alkynes, were selectively generated from alkynes and CF3I by environmentally benign and efficient visible-light photoredox catalysis. Subtle differences in the combination of catalyst, base, and solvent enabled the control of reactivity and selectivity for the reaction between an alkyne and CF3I.
- URI
- http://onlinelibrary.wiley.com/doi/10.1002/ange.201308735/fullhttp://hdl.handle.net/20.500.11754/47279
- ISSN
- 1433-7851
- DOI
- 10.1002/ange.201308735
- Appears in Collections:
- GRADUATE SCHOOL[S](대학원) > BIONANOTECHNOLOGY(바이오나노학과) > Articles
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