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Hydrogen storage in Li dispersed graphene with Stone-Wales defects: A first-principles study

Title
Hydrogen storage in Li dispersed graphene with Stone-Wales defects: A first-principles study
Author
정용재
Keywords
Hydrogen; storageStone-Wales; defectGrapheneDensity; functional; theoryAb; initio
Issue Date
2014-08
Publisher
Elsevier Science B.V., Amsterdam.
Citation
International journal of hydrogen energy, 2014, 39(25), pp. 13189-13194
Abstract
Li dispersed graphene with Stone?Wales (SW) defects was investigated for geometric stability and hydrogen storage capability using density functional theory (DFT) calculations. When the graphene with SW defects, which has the internal strain derived from rotated C?C bond, adsorbs Li adatoms, the strain is relieved by generating the buckling of graphene. This effect plays a crucial role in enhancing the binding energy (Eb) of Li adatoms, consequently allowing the atomic dispersion of Li adatoms on the graphene without clustering. The Li dispersed graphene with SW defects can accommodate four H2 molecules with the range of 0.20?0.35 eV. This falls in a desirable range for feasible applications under ambient conditions. It is therefore anticipated that Li dispersed graphene with SW defects may be an ideal hydrogen storage media due to its geometric stability and high hydrogen storage capacity.
URI
http://www.sciencedirect.com/science/article/pii/S0360319914019065?via%3Dihubhttp://hdl.handle.net/20.500.11754/46887
ISSN
0360-3199
DOI
10.1016/j.ijhydene.2014.06.163
Appears in Collections:
COLLEGE OF ENGINEERING[S](공과대학) > MATERIALS SCIENCE AND ENGINEERING(신소재공학부) > Articles
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