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dc.contributor.author윤소원-
dc.date.accessioned2018-03-14T08:33:18Z-
dc.date.available2018-03-14T08:33:18Z-
dc.date.issued2014-07-
dc.identifier.citationOrganic Letters, Jul 2014, 16(14), P.3720-3723,en_US
dc.identifier.issn1523-7060-
dc.identifier.urihttps://pubs.acs.org/doi/10.1021/ol5015398-
dc.description.abstractAn effective metal-free C-H amination of N-Ts-2-alkenylanilines by using DDQ as an oxidant has been developed to afford a diverse range of substituted indoles. This protocol is operationally simple and robust, obviates the need of expensive transition-metal catalysts, and offers a broad substrate scope. A mechanism involving a radical cation generated by SET and a migratorial process via a phenonium ion intermediate is proposed.en_US
dc.description.sponsorshipThis work was supported by both Basic Science Research Program and Nano.Material Technology Department Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education and MSIP (Nos. 2012R1A1A2041471, 2012M3A7B4049654, and 2014-011165).en_US
dc.language.isoko_KRen_US
dc.publisherAmer Chemical SOCen_US
dc.subjectPALLADIUM-CATALYZED REACTIONSen_US
dc.subjectHYPERVALENT IODINE REAGENTSen_US
dc.subject2,3-DICHLORO-5,6-DICYANO-1,4-BENZOQUINONE DDQen_US
dc.subject4-SUBSTITUTED INDOLESen_US
dc.subjectHIGHLY EFFICIENTen_US
dc.subjectMILD CONDITIONSen_US
dc.subjectSTYRYL AZIDESen_US
dc.subjectPHENONIUM IONen_US
dc.subjectOXIDATIONen_US
dc.subjectFUNCTIONALIZATIONen_US
dc.titleMetal-Free C-H Amination for Indole Synthesisen_US
dc.typeArticleen_US
dc.relation.no14-
dc.relation.volume16-
dc.identifier.doi10.1021/ol5015398-
dc.relation.page3720-3723-
dc.relation.journalORGANIC LETTERS-
dc.contributor.googleauthorYoun, So Won-
dc.relation.code2014037111-
dc.sector.campusS-
dc.sector.daehakCOLLEGE OF NATURAL SCIENCES[S]-
dc.sector.departmentDEPARTMENT OF CHEMISTRY-
dc.identifier.pidsowony73-
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COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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