Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 윤소원 | - |
dc.date.accessioned | 2018-03-14T08:33:18Z | - |
dc.date.available | 2018-03-14T08:33:18Z | - |
dc.date.issued | 2014-07 | - |
dc.identifier.citation | Organic Letters, Jul 2014, 16(14), P.3720-3723, | en_US |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/ol5015398 | - |
dc.description.abstract | An effective metal-free C-H amination of N-Ts-2-alkenylanilines by using DDQ as an oxidant has been developed to afford a diverse range of substituted indoles. This protocol is operationally simple and robust, obviates the need of expensive transition-metal catalysts, and offers a broad substrate scope. A mechanism involving a radical cation generated by SET and a migratorial process via a phenonium ion intermediate is proposed. | en_US |
dc.description.sponsorship | This work was supported by both Basic Science Research Program and Nano.Material Technology Department Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education and MSIP (Nos. 2012R1A1A2041471, 2012M3A7B4049654, and 2014-011165). | en_US |
dc.language.iso | ko_KR | en_US |
dc.publisher | Amer Chemical SOC | en_US |
dc.subject | PALLADIUM-CATALYZED REACTIONS | en_US |
dc.subject | HYPERVALENT IODINE REAGENTS | en_US |
dc.subject | 2,3-DICHLORO-5,6-DICYANO-1,4-BENZOQUINONE DDQ | en_US |
dc.subject | 4-SUBSTITUTED INDOLES | en_US |
dc.subject | HIGHLY EFFICIENT | en_US |
dc.subject | MILD CONDITIONS | en_US |
dc.subject | STYRYL AZIDES | en_US |
dc.subject | PHENONIUM ION | en_US |
dc.subject | OXIDATION | en_US |
dc.subject | FUNCTIONALIZATION | en_US |
dc.title | Metal-Free C-H Amination for Indole Synthesis | en_US |
dc.type | Article | en_US |
dc.relation.no | 14 | - |
dc.relation.volume | 16 | - |
dc.identifier.doi | 10.1021/ol5015398 | - |
dc.relation.page | 3720-3723 | - |
dc.relation.journal | ORGANIC LETTERS | - |
dc.contributor.googleauthor | Youn, So Won | - |
dc.relation.code | 2014037111 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF NATURAL SCIENCES[S] | - |
dc.sector.department | DEPARTMENT OF CHEMISTRY | - |
dc.identifier.pid | sowony73 | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.