Pd/C Catalyzed Oxidation of Secondary Benzylic Alcohols using Chlorobenzene under an Inert Condition

Abstract

For several reasons, typical diesel oxidation catalysts (DOCs) contain a mixture of Pt and Pd and in this study, the effect of the Pt:Pd ratio on a DOC's ability to oxidize CO and different hydrocarbon types was investigated. The concentrations and types of pollutant species were used to-simulate those found in low temperature combustion (LTC) engine exhaust. Representative hydrocarbon species were selected; C2H4 (short-chain alkene), C2H6 (short-chain alkane), C6H4 (long-chain alkane) and C2H8 (aromatic). Two types of experiments were performed, one in which the oxidation of each hydrocarbon or CO reactant was examined individually (simple feed conditions), and the second in which all reactants were added together (full feed conditions). Under the simple feed conditions, CO and C2H6 oxidation increased with increasing Pd content, while C2H4 and C6H14 oxidation improved with higher Pt content. When the full mixture of CO and hydrocarbons was used, hydrocarbon oxidation light off consistently followed that of CO, regardless of the Pt:Pd ratio, due to strong inhibition by CO. The best CO oxidation activity was observed over the Pd-only catalyst, and performance over the bimetallic samples was a function of both CO inhibition and Pt:Pd ratio. More specifically, as Pd content increased, CO inhibition was dampened, and as Pt content increased its inherent activity toward alkene oxidation became significant. Since inhibition is a function of the Pt/Pd content and the individual metals have different inherent activities toward the oxidation of different hydrocarbons, results obtained from the experiments with the simple feed could not be directly correlated to those from the experiments with the mixture of hydrocarbons. (C) 2017 Elsevier B.V. All rights reserved.