The cooperative FeCl3/DDQ system for the regioselective synthesis of 3-arylindoles from beta-monosubstituted 2-alkenylanilines
- Title
- The cooperative FeCl3/DDQ system for the regioselective synthesis of 3-arylindoles from beta-monosubstituted 2-alkenylanilines
- Author
- 윤소원
- Keywords
- C-H AMINATION; 3-SUBSTITUTED INDOLES; ANNULATION; INHIBITORS; PHENOLS; ALKENES; HYDROAMINATION; ACTIVATION; CATALYSIS; ENAMINES
- Issue Date
- 2016-02
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- ORGANIC & BIOMOLECULAR CHEMISTRY, v. 14, NO 7, Page. 2200-2204
- Abstract
- A highly regioselective synthesis of 3-arylindoles by using the cooperative FeCl3/DDQ system has been developed. This new protocol represents an attractive route for the synthesis of 3-arylindoles from readily accessible non-indole precursors, beta-arylsubstituted 2-styrylanilines, using an inexpensive catalyst and oxidant. Noteworthy is the unique synergetic and synergistic effect of FeCl3 and DDQ on the 1,2-aryl migratory process.
- URI
- http://pubs.rsc.org/en/Content/ArticleLanding/2016/OB/C6OB00074F#!divAbstracthttp://hdl.handle.net/20.500.11754/31885
- ISSN
- 1477-0520; 1477-0539
- DOI
- 10.1039/c6ob00074f
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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