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Enhancing Electrocatalytic Hydrogen Evolution by Nickel Salicylaldimine Complexes with Alkali Metal Cations in Aqueous Media

Title
Enhancing Electrocatalytic Hydrogen Evolution by Nickel Salicylaldimine Complexes with Alkali Metal Cations in Aqueous Media
Author
Tran, Phong Dinh
Keywords
MOLECULAR CATALYSIS; CYCLIC VOLTAMMETRY; CARBON-DIOXIDE; VISIBLE-LIGHT; H-2 EVOLUTION; WATER; GENERATION; REDUCTION; CO; PORPHYRINS
Issue Date
2016-01
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v. 54, no. 14, page 2948-2951
Abstract
New salicylaldimine nickel complexes, comprising only earth-abundant elements, have been developed for electrocatalytic hydrogen evolution in aqueous media. The second-sphere ether functionalities on the periphery of the complexes enhance the electrocatalytic activity in the presence of alkali metal cations. The electrocatalysts demonstrate improved performances especially in the economical and sustainable seawater reaction medium.
URI
http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C5CC09456A#!divAbstracthttp://hdl.handle.net/20.500.11754/30573
ISSN
1359-7345; 1364-548X
DOI
10.1039/c5cc09456a
Appears in Collections:
COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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