Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 민선준 | - |
dc.date.accessioned | 2024-08-12T05:34:52Z | - |
dc.date.available | 2024-08-12T05:34:52Z | - |
dc.date.issued | 2022-08-30 | - |
dc.identifier.citation | ACS APPLIED MATERIALS & INTERFACES, v. 14, no 36, page. 40967-40974 | en_US |
dc.identifier.issn | 1944-8244 | en_US |
dc.identifier.issn | 1944-8252 | en_US |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acsami.2c10530 | en_US |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/191545 | - |
dc.description.abstract | Solar-thermal materials absorb sunlight and convert it into heat, which is released into the surrounding medium. Utilization of solar energy for solvent heating can be a potential method of eco-friendly organic reactions. However, to date, significant heating of the entire volume of a solvent by 1 sun illumination has not been reported. In the present work, a network structure of solar-thermal materials has been proposed for zero energy heating of a solvent under 1 sun illumination. A network-structured solar-thermal material with an additional catalytic function was fabricated by sputtering palladium into a melamine sponge. The nanocrystalline palladium-decorated melamine sponge (Pd-sponge) has excellent sunlight absorption properties in the entire wavelength range that enable efficient solar-thermal conversion. The Pd-sponge can reduce heat loss to the surroundings by effectively blocking thermal radiation from the heated solvent. The temperature of the reaction solution with the ethanol-water mixture filled in the Pd-sponge increased from 23 to 59 degrees C under 1 sun illumination. The elevated temperature of the reaction solutions by solar-thermal conversion successfully accelerated the heterogeneous Pd-catalyzed Suzuki coupling reactions with high conversions. Easy and low-energy-consuming multicycle use of the solar-thermal and catalytic properties of the Pd-sponge has also been demonstrated. | en_US |
dc.description.sponsorship | This work was supported by the Basic Research Program through the National Research Foundation of Korea (NRF) funded by the MSIT (2020R1A4A4079870) and the GRRC program of Gyeonggi province (GRRCHanyang2020-B01). | en_US |
dc.language | en_US | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.relation.ispartofseries | v. 14, no 36;40967-40974 | - |
dc.subject | solar-thermal effect | en_US |
dc.subject | network structure, eco-friendly reaction | en_US |
dc.subject | Pd catalyst | en_US |
dc.subject | Suzuki reaction | en_US |
dc.title | Zero Energy Heating of Solvent with Network-Structured Solar-Thermal Material: Eco-Friendly Palladium Catalysis of the Suzuki Reaction | en_US |
dc.type | Article | en_US |
dc.relation.no | 36 | - |
dc.relation.volume | 14 | - |
dc.identifier.doi | https://doi.org/10.1021/acsami.2c10530 | en_US |
dc.relation.page | 40967-40974 | - |
dc.relation.journal | ACS APPLIED MATERIALS & INTERFACES | - |
dc.contributor.googleauthor | Park, Seungbeom | - |
dc.contributor.googleauthor | Park, Woomin | - |
dc.contributor.googleauthor | Lee, Kangjoo | - |
dc.contributor.googleauthor | Min, Sun-Joon | - |
dc.contributor.googleauthor | Jang, Kwang-Suk | - |
dc.relation.code | 2022043993 | - |
dc.sector.campus | E | - |
dc.sector.daehak | COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E] | - |
dc.sector.department | DEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING | - |
dc.identifier.pid | sjmin | - |
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