Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 전형필 | - |
dc.date.accessioned | 2023-07-24T04:07:44Z | - |
dc.date.available | 2023-07-24T04:07:44Z | - |
dc.date.issued | 2010-12 | - |
dc.identifier.citation | Inorganic Chemistry, v. 49, NO. 23, Page. 10833-10839 | - |
dc.identifier.issn | 0020-1669;1520-510X | - |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/ic1012523 | en_US |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/184322 | - |
dc.description.abstract | A simple and multitopic ligand, pyrimidine-5-carboxylate (pmc), has been used to obtain a series of metal organic frameworks (MOFs) based on Co2+, Cd2+, and Cu2+. The networks possess well-defined topologies of body-centered-cubic, rutile, and interpenetrated NbO structures, respectively. Among those, [Cu(pmc)(2)] possesses a permanent porosity resulting from straight one-dimensional channels of 5.5 angstrom free passages. Unexpectedly, this porous MOF displays a highly selective sorption behavior for CO2, and the sorptions of N-2, Ar, O-2, H-2, and CH4 at two different temperatures are found to be negligible. The results of diffraction and spectroscopic analyses exclude framework dynamics or incomplete evacuation as the origin of the gas-sorption selectivity. | - |
dc.description.sponsorship | This research was supported by the Basic Science Research Program through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology (Grant 2009-0087194). We thank the Pohang Accelerator Laboratory for beamline use (2009-1063-05). H.C. is grateful to Prof. K. Kim (POSTECH, Korea) for allowing access to PXRD. | - |
dc.language | en | - |
dc.publisher | American Chemical Society | - |
dc.title | Topologies of Metal-Organic Frameworks Based on Pyrimidine-5-carboxylate and Unexpected Gas-Sorption Selectivity for CO2 | - |
dc.type | Article | - |
dc.relation.no | 23 | - |
dc.relation.volume | 49 | - |
dc.identifier.doi | 10.1021/ic1012523 | - |
dc.relation.page | 10833-10839 | - |
dc.relation.journal | Inorganic Chemistry | - |
dc.contributor.googleauthor | Seo, Jinwoo | - |
dc.contributor.googleauthor | Jin, Narae | - |
dc.contributor.googleauthor | Chun, Hyungphil | - |
dc.sector.campus | E | - |
dc.sector.daehak | 과학기술융합대학 | - |
dc.sector.department | 화학분자공학과 | - |
dc.identifier.pid | hchun | - |
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