Full metadata record
DC Field | Value | Language |
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dc.contributor.author | 이용우 | - |
dc.date.accessioned | 2023-07-24T01:05:32Z | - |
dc.date.available | 2023-07-24T01:05:32Z | - |
dc.date.issued | 2012-11 | - |
dc.identifier.citation | Bulletin of the Korean Chemical Society, v. 33, NO. 11, Page. 3657-3664 | - |
dc.identifier.issn | 0253-2964;1229-5949 | - |
dc.identifier.uri | http://koreascience.or.kr/article/JAKO201236135723022.page | en_US |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/184165 | - |
dc.description.abstract | Reactions of 1-adamantylmethyl chloroformate (1-AdCH2OCOCl, 1) and 1-adamantylmethyl fluoroformate (1-AdCH2OCOF, 2) in hydroxylic solvents have been studied. Application of the extended Grunwald-Winstein (G-W) equation to solvolyses of 1 in a variety of pure and binary solvents indicates an addition-elimination pathway in the majority of the solvents except an ionization pathway in the solvents of relatively low nucleophilcity and high ionizing power. The solvolyses of 2 show an addition-elimination pathway in all of the mixed solvents. The leaving group effects (kF/kCl), the kinetic solvent isotope effects (KSIEs, kMeOH/kMeOD), and the enthalpy and entropy of activation for the solvolyses of 1 and 2 were also calculated. The selectivity values (S) for each solvent composition are reported and discussed. These observations are compared with those previously reported for other alkyl haloformate esters. | - |
dc.language | en | - |
dc.publisher | 대한화학회 | - |
dc.subject | 1-Adamantylmethyl haloformates | - |
dc.subject | Grunwald-Winstein equation | - |
dc.subject | Leaving group effect | - |
dc.subject | Solvent isotope effect | - |
dc.title | Rate and Product Studies of 1-Adamantylmethyl Haloformates Under Solvolytic Conditions | - |
dc.type | Article | - |
dc.relation.no | 11 | - |
dc.relation.volume | 33 | - |
dc.identifier.doi | 10.5012/bkcs.2012.33.11.3657 | - |
dc.relation.page | 3657-3664 | - |
dc.relation.journal | Bulletin of the Korean Chemical Society | - |
dc.contributor.googleauthor | Park, Kyoungho | - |
dc.contributor.googleauthor | Lee, Yelin | - |
dc.contributor.googleauthor | Lee, Yong woo | - |
dc.contributor.googleauthor | Kyoug, Jin burm | - |
dc.contributor.googleauthor | Kevill, Dennis N. | - |
dc.sector.campus | E | - |
dc.sector.daehak | 과학기술융합대학 | - |
dc.sector.department | 화학분자공학과 | - |
dc.identifier.pid | yongwoolee | - |
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