Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 원호식 | - |
dc.date.accessioned | 2023-07-21T05:24:48Z | - |
dc.date.available | 2023-07-21T05:24:48Z | - |
dc.date.issued | 2010-05 | - |
dc.identifier.citation | Bulletin of the Korean Chemical Society, v. 31, NO. 5, Page. 1209-1214 | - |
dc.identifier.issn | 0253-2964;1229-5949 | - |
dc.identifier.uri | http://koreascience.or.kr/article/JAKO201014752579156.page | en_US |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/184143 | - |
dc.description.abstract | Reactions of 2-methyl-2-chloroadamantane (1) in a variety of pure and binary solvents have been studied at various temperatures and pressures up to 80 MPa. The sensitivity (m) to changes in solvent ionizing power of the Grunwald-Winstein equation, and the activation volume (Delta V-double dagger) are calculated from the specific rates. An excellent linear relationship (R = 0.997) for 1, log (k/k(0))= 0.80Y(Cl) + 0.11, and the activation volume, Delta V-double dagger = -15.2 similar to-10.2 mL.mol(-1) were observed. These values are similar to those for solvolyses of 1-adamantyl halides over the full range of solvents, suggesting that the unimolecular mechanism involving ion pairs is rate-determining. These observations arc also compared with those previously reported for the corresponding 1-adamantyl derivatives and chloroformate esters. | - |
dc.description.sponsorship | This paper was supported by Korean Council for University Education, grant funded by Korean Government (MOEHRD) for 2008 Domestic Faculty Exchange. | - |
dc.language | en | - |
dc.publisher | 대한화학회 | - |
dc.subject | 2-Methyl-2-chloroadamantane | - |
dc.subject | Grunwald-Winstein equation | - |
dc.subject | Activation volume | - |
dc.title | Rate and Product Studies with 2-Methyl-2-Chloroadamantane under Solvolytic Conditions | - |
dc.type | Article | - |
dc.relation.no | 5 | - |
dc.relation.volume | 31 | - |
dc.identifier.doi | 10.5012/bkcs.2010.31.5.1209 | - |
dc.relation.page | 1209-1214 | - |
dc.relation.journal | Bulletin of the Korean Chemical Society | - |
dc.contributor.googleauthor | Lee, Young Hoon | - |
dc.contributor.googleauthor | Seong, Mi Hye | - |
dc.contributor.googleauthor | Lee, Eun Sung | - |
dc.contributor.googleauthor | Lee, Yong-Woo | - |
dc.contributor.googleauthor | Won, Hoshik | - |
dc.contributor.googleauthor | Kyong, Jin Burm | - |
dc.contributor.googleauthor | Kevill, Dennis N. | - |
dc.sector.campus | E | - |
dc.sector.daehak | 과학기술융합대학 | - |
dc.sector.department | 화학분자공학과 | - |
dc.identifier.pid | hswon | - |
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