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dc.contributor.author김기현-
dc.date.accessioned2022-11-14T04:30:55Z-
dc.date.available2022-11-14T04:30:55Z-
dc.date.issued2022-01-
dc.identifier.citationChemical Engineering Journal, v. 428, article no. 131177, Page. 1-16en_US
dc.identifier.issn1385-8947;1873-3212en_US
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S1385894721027583?via%3Dihuben_US
dc.identifier.urihttps://repository.hanyang.ac.kr/handle/20.500.11754/176685-
dc.description.abstractCatalytic oxidation of pollutant(s) into innocuous end products (carbon dioxide (CO2) and water) without heat or light sources is an ideal option for air quality management. In pursuit of such goal, platinum (Pt) supported by waste eggshell (biogenic calcium carbonate), namely Pt/eggshell, is synthesized through a simple wetness impregnation approach to catalyze 100 ppm formaldehyde (FA) into CO2 at room temperature (RT: 30 °C). The co-impregnation of potassium (K) alongside Pt leads to a full-sclae (100%) enhancement in the net catalytic activity to destruct FA. The in-situ diffuse reflectance infrared Fourier transform spectroscopy analysis suggests the FA oxidation pathway to involve dioxymethylene, formate, and carbon monoxide intermediates. The FA reaction pathways and associated mechanisms are also accounted for based on the density functional theory simulations. This study opens a new path for developing high-performance biowaste-derived catalysts for the complete mineralization of gaseous FA without the supply of external energy sources.en_US
dc.description.sponsorshipThis work was supported by a grant from the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ITC (MSIT) of Korean government (Grant No: 2021R1A3B1068304). This study was also supported by the Korea Ministry of Environment (MOE) as part of the “Technology Program for Establishing Biocide Safety Management” (2018002490001). DWB acknowledges support from the Ministry of Science and Higher Education of the Russian Federation (through the basic part of the government mandate, Project No. FEUZ-2020-0060).en_US
dc.languageenen_US
dc.publisherElsevier B.V.en_US
dc.subjectBiowasteen_US
dc.subjectCatalysisen_US
dc.subjectFormaldehydeen_US
dc.subjectIndoor airen_US
dc.subjectVolatile organic compoundsen_US
dc.titleDeep oxidation of gaseous formaldehyde at room-temperature by a durable catalyst formed through the controlled addition of potassium to platinum supported on waste eggshellen_US
dc.typeArticleen_US
dc.relation.volume428-
dc.identifier.doi10.1016/j.cej.2021.131177en_US
dc.relation.page1-16-
dc.relation.journalChemical Engineering Journal-
dc.contributor.googleauthorVikrant, Kumar-
dc.contributor.googleauthorKim, Ki-Hyun-
dc.contributor.googleauthorDong, Fan-
dc.contributor.googleauthorBoukhvalov, Danil W.-
dc.contributor.googleauthorChoi, Wonyong-
dc.sector.campusS-
dc.sector.daehak공과대학-
dc.sector.department건설환경공학과-
dc.identifier.pidkkim61-
Appears in Collections:
COLLEGE OF ENGINEERING[S](공과대학) > CIVIL AND ENVIRONMENTAL ENGINEERING(건설환경공학과) > Articles
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