ECO-Degradable and Flexible Solid-State Ionic Conductors by Clay-Nanoconfined DMSO Composites
- Title
- ECO-Degradable and Flexible Solid-State Ionic Conductors by Clay-Nanoconfined DMSO Composites
- Author
- 위정재
- Keywords
- biodegradable; composites; eco-friendly materials; ionic conductivity; montmorillonite; nacre-mimetic; solid-state electrolytes
- Issue Date
- 2020-03
- Publisher
- WILEY-V C H VERLAG GMBH
- Citation
- ADVANCED SUSTAINABLE SYSTEMS, v. 4, no. 5, article no. 1900134
- Abstract
- Solid-state electrolytes can alleviate the safety issues of electrochemical energy systems related to chemical and thermal instabilities of liquid electrolytes. While a liquid provides seamless ionic transport with almost perfect wettability between electrodes, a solid-state electrolyte needs to demonstrate at least comparable electrochemical performance to liquid electrolytes as well as mechanical robustness and flexibility. Here, the facile preparation of montmorillonite (MMT)/dimethyl sulfoxide (DMSO) nanocomposites is reported, which show high ionic conductivities, mechanical strengths, and thermal stabilities by forming nacre-mimetic "brick-and-mortar" structures. The molecularly confined structures of DMSO are confirmed by X-ray diffraction peaks with d-spacings of interplanar spacing that are slightly larger than MMTs. The MMT/DMSO composites have mechanical strengths and toughnesses of 55.3 +/- 4.8 MPa and 210.2 +/- 32.6 kJ m(-2), respectively. The ionic conductivity is approximate to 2 x 10(-4) S cm(-1) at room temperature, and their thermal stability is in the range of -100 to 120 degrees C. The optical translucency, on-demand eco-degradability, and solution processability together make the MMT/DMSO composites unique materials with a wide range of solid-state electrochemical applications including batteries.
- URI
- https://onlinelibrary.wiley.com/doi/10.1002/adsu.201900134https://repository.hanyang.ac.kr/handle/20.500.11754/175127
- ISSN
- 2366-7486
- DOI
- 10.1002/adsu.201900134
- Appears in Collections:
- COLLEGE OF ENGINEERING[S](공과대학) > ORGANIC AND NANO ENGINEERING(유기나노공학과) > Articles
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