Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 하산 르가즈 | - |
dc.date.accessioned | 2022-08-11T01:50:04Z | - |
dc.date.available | 2022-08-11T01:50:04Z | - |
dc.date.issued | 2021-10 | - |
dc.identifier.citation | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, v. 626, Page. 127047-127047 | en_US |
dc.identifier.issn | 0927-7757 | - |
dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S092777572100916X | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/172369 | - |
dc.description.abstract | Corrosion protection of carbon steel (CS) is an important challenge in the industry field. The search for an effective protection approach is still a hot research question. In the present work, three hydrazone derivatives (HZ-OH, HZ-Me, and HZ-Cl) were used in 1.0 M HCl solution for API grade CS corrosion mitigation. Their corrosion inhibition performance was evaluated by electrochemical tests while steel surface was analyzed by Xray photoelectron spectroscopy (XPS), contact angle and scanning electron microscope (SEM). Electrochemical tests showed an inhibition efficiency between 91% and 98% for CS exposed to acidic solution containing 0.05 mol/L of the three hydrazone derivatives. All compounds were classified as mixed type inhibitors, inhibiting both cathodic and anodic corrosion reactions. XPS showed that inhibitor molecules formed a stable layer on steel surface through chemical and physical interactions. The adsorption of molecules onto the steel surface was found to follow Langmuir model. DFT and MD simulations were used to investigate the interaction of hydrazones with Fen (n = 1-4) and Fe2O3(001) surface, respectively. They confirmed that the inhibitor with two hydroxy groups (HZ-OH) had a greater interaction with iron atoms. | en_US |
dc.description.sponsorship | This research was supported by basic science research program through the National Research Foundation (NRF) of Korea funded by the Ministry of Science, ICT and Future Planning (No. 2015R1A5A1037548). The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for funding this work through research groups program under grant number R.G. P-2/56/42. Authors are grateful to technical assistance from “Centre de Recherche en Technologie des Semi-conducteurs pour l’ ́energ ́etique” CRTSE especially Mr. Hocine CHERAGA and Centre de Recherche Scientifique et Technique en Analyses Physico- Chimiques CRAPC, Algeria. | en_US |
dc.language.iso | en | en_US |
dc.publisher | ELSEVIER | en_US |
dc.subject | Corrosion inhibition | en_US |
dc.subject | Hydrazone | en_US |
dc.subject | Mild steel | en_US |
dc.subject | DFT | en_US |
dc.subject | XPS | en_US |
dc.subject | Molecular dynamics | en_US |
dc.title | Hydrazone-based green corrosion inhibitors for API grade carbon steel in HCl: Insights from electrochemical, XPS, and computational studies | en_US |
dc.type | Article | en_US |
dc.relation.volume | 626 | - |
dc.identifier.doi | 10.1016/j.colsurfa.2021.127047 | - |
dc.relation.page | 127047-127047 | - |
dc.relation.journal | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | - |
dc.contributor.googleauthor | Khamaysa, Oday Mohammad Ahmad | - |
dc.contributor.googleauthor | Selatnia, Ilhem | - |
dc.contributor.googleauthor | Lgaz, Hassane | - |
dc.contributor.googleauthor | Sid, Assia | - |
dc.contributor.googleauthor | Lee, Han-Seung | - |
dc.contributor.googleauthor | Zeghache, Hadjer | - |
dc.contributor.googleauthor | Benahmed, Merzoug | - |
dc.contributor.googleauthor | Ali, Ismat H. | - |
dc.contributor.googleauthor | Mosset, Paul | - |
dc.relation.code | 2021009293 | - |
dc.sector.campus | E | - |
dc.sector.daehak | OFFICE OF ACADEMIC AFFAIRS[E] | - |
dc.sector.department | CENTER FOR CREATIVE CONVERGENCE EDUCATION | - |
dc.identifier.pid | hlgaz | - |
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