Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김기현 | - |
dc.date.accessioned | 2021-07-20T01:09:37Z | - |
dc.date.available | 2021-07-20T01:09:37Z | - |
dc.date.issued | 2020-03 | - |
dc.identifier.citation | ADVANCES IN COLLOID AND INTERFACE SCIENCE, v. 277, article no. 102108 | en_US |
dc.identifier.issn | 0001-8686 | - |
dc.identifier.issn | 1873-3727 | - |
dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S0001868619304154?via%3Dihub | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/162815 | - |
dc.description.abstract | Recently, as a new sub-family of porous coordination polymers (PCPs), porphyrinic-MOFs (Porph-MOFs) with biomimetic features have been developed using porphyrin macrocycles as ligands and/or pillared linkers. The control over the coordination of the porphyrin ligand and its derivatives however remains a challenge for engineering new tunable Porph-MOF frameworks by self-assembly methods. The key challenges exist in the following respects: (i) collapse of the large open pores of Porph-MOFs during synthesis, (ii) deactivation of unsaturated metal-sites (UMCs) by axial coordination, and (iii) the tendency of both coordinated moieties (at peripheral meso- and beta-carbon sites) and the N-4-pyridine core to coordinate with metal cations. In this respect, this review covers the advances in the design of Porph-MOFs relative to their counterpart covalent organic frameworks (Porph-COFs). The potential utility of custom-designed porphyrin/metalloporphyrins ligands is highlighted. Synthesis strategies of Porph-MOFs are also illustrated with modular design of hybrid guest@host composites (either Porph@MOFs or guest@Porph-MOFs) with exceptional topologies and stability. This review summarizes the synergistic benefits of coordinated porphyrin ligands and functional guest molecules in Porph-MOF composites for enhanced catalytic performance in various redox applications. This review shed lights on the engineering of new tunable hetero-metals open active sites within (metallo)porphyrin-MOFs as out-of-the-box platforms for enhanced catalytic processes in chemical and biological media. | en_US |
dc.description.sponsorship | We would like to acknowledge support from the R&D Center for Green Patrol Technologies through the R&D for Global Top Environmental Technologies funded by the Ministry of Environment (MOE), as well as by a grant from the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT, & Future Planning (Grant No: 2016R1E1A1A01940995). | en_US |
dc.language.iso | en | en_US |
dc.publisher | ELSEVIER | en_US |
dc.subject | Metal-organic frameworks (MOFs) | en_US |
dc.subject | Metalloporphyrin coordination | en_US |
dc.subject | Metalloporphyrin-MOFs composites | en_US |
dc.subject | Modulation strategies | en_US |
dc.subject | Catalysis applications | en_US |
dc.title | Metalloporphyrinic metal-organic frameworks: Controlled synthesis for catalytic applications in environmental and biological media | en_US |
dc.type | Article | en_US |
dc.relation.volume | 277 | - |
dc.identifier.doi | 10.1016/j.cis.2020.102108 | - |
dc.relation.page | 1-53 | - |
dc.relation.journal | ADVANCES IN COLLOID AND INTERFACE SCIENCE | - |
dc.contributor.googleauthor | Younis, Sherif A. | - |
dc.contributor.googleauthor | Lim, Dong-Kwon | - |
dc.contributor.googleauthor | Kim, Ki-Hyun | - |
dc.contributor.googleauthor | Deep, Akash | - |
dc.relation.code | 2020047803 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF ENGINEERING[S] | - |
dc.sector.department | DEPARTMENT OF CIVIL AND ENVIRONMENTAL ENGINEERING | - |
dc.identifier.pid | kkim61 | - |
dc.identifier.researcherID | I-8499-2018 | - |
dc.identifier.orcid | https://orcid.org/0000-0003-0487-4242 | - |
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