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A new Zr-rich intermetallic phase in an Al-14Si-3Cu-4.5Ni casting alloy with trace additions of Zr

Title
A new Zr-rich intermetallic phase in an Al-14Si-3Cu-4.5Ni casting alloy with trace additions of Zr
Author
장재일
Keywords
Al-Si casting alloy; Multicomponent; Zr-rich intermetallics; Microstructure characterization; High temperature mechanical properties; Nucleation
Issue Date
2020-02
Publisher
ELSEVIER SCI LTD
Citation
INTERMETALLICS, v. 117, article no. 106667
Abstract
A trace addition of Zr to a multicomponent Al-14Si-3Cu-4.5Ni casting alloy has often been found to form a coarse plate-like Zr-rich intermetallic compound with a size of a few tens of mu m at the beginning of solidification. Evaluation of the phase composition has confirmed that the Zr-rich intermetallic phase consists of multicomponent constituent elements, mainly Al, Si, Ni and Fe, and is present in a form of (Al,Si)(3)(Zr,Ni,Fe). The existence of such a complex (Al,Si)(3)(Zr,NLFe) phase has not yet been predicted by phase equilibria calculation of the multicomponent Al-14Si-CuNiMg systems. In this paper, transmission electron microscopy studies combined with electron backscattered diffraction pattern analysis reveals the crystallography information of the (Al,Si)(3)(Zr, Ni,Fe) phase for the first time and identifies it as a modified Al3Zr-D023 crystal (tetragonal, I4/mmm(139)) with slightly changed lattice parameters of a = b = 3.275 angstrom and c = 15.475 angstrom. The primary (Al,Si)(3)(Zr,Ni,Fe) phase is found to nucleate directly onto AlP partides. The mechanical properties of the Zr-rich intermetallics were also investigated using nanoindentation at both room and elevated temperatures and were compared to those of the Si phase.
URI
https://www.sciencedirect.com/science/article/pii/S0966979519308763?via%3Dihubhttps://repository.hanyang.ac.kr/handle/20.500.11754/161556
ISSN
0966-9795; 1879-0216
DOI
10.1016/j.intermet.2019.106667
Appears in Collections:
COLLEGE OF ENGINEERING[S](공과대학) > MATERIALS SCIENCE AND ENGINEERING(신소재공학부) > Articles
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