Mini-Pilot Scale Production of Homopolymer and Block Copolymer by Anionic Polymerization
- Title
- Mini-Pilot Scale Production of Homopolymer and Block Copolymer by Anionic Polymerization
- Author
- 박융호
- Keywords
- anionic polymerization; scale-up; homopolymer; block copolymer; controlled molecular weight; low polydispersity index
- Issue Date
- 2001-07
- Publisher
- KOREAN SOC INDUSTRIAL ENGINEERING CHEMISTRY
- Citation
- Journal of Industrial and Engineering Chemistry, v. 7, no. 4, page. 204-211
- Abstract
- In order to obtain a large amount of polymer samples with a well-controlled molecular weight and polydispersity index, a bench scale reactor system for anionic polymerization was built instead of the traditional break-seal method. Homopolymers were successfully prepared from non-polar monomers in amounts of 40 similar to 350 g with well-defined structures. The major process variables were found to be the type of initiator, monomer concentration. and the volume of the reaction mixture. When a higher monomer concentration or larger reaction mixture volume was used, the removal of reaction heat became critical. In the case of a polar monomer, close control of the anionic polymerization was required to obtain a lower PDI. In the preparation of a diene-acryl block copolymer, it was found that the thorough removal of any impurities from the second monomer was critical for suppressing the generation of a homopolymer.
- URI
- https://www.cheric.org/research/tech/periodicals/view.php?seq=314631https://repository.hanyang.ac.kr/handle/20.500.11754/158565
- ISSN
- 1226-086X; 1876-794X
- Appears in Collections:
- COLLEGE OF ENGINEERING SCIENCES[E](공학대학) > MATERIALS SCIENCE AND CHEMICAL ENGINEERING(재료화학공학과) > Articles
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