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dc.contributor.author경진범-
dc.date.accessioned2020-11-13T02:26:26Z-
dc.date.available2020-11-13T02:26:26Z-
dc.date.issued2003-03-
dc.identifier.citationJOURNAL OF ORGANIC CHEMISTRY, v. 68, issue. 9, page. 3425-3432en_US
dc.identifier.issn0022-3263-
dc.identifier.urihttps://pubs.acs.org/doi/10.1021/jo0207426-
dc.identifier.urihttps://repository.hanyang.ac.kr/handle/20.500.11754/155523-
dc.description.abstractReaction of 2-adamantyl chloroformate under a variety of solvolytic conditions leads to 2-adamantyl chloride accompanied by solvolysis products, some with and some without retention of the CO2 unit. For example, in 100% ethanol, only 4.8% 2-adamantyl chloride is formed with the mixed carbonate (88%) being the dominant product, and in 100% 2,2,2-trifluoroethanol, the products are both formed with loss of CO2, 59% of the chloride and 41% of the ether. With exclusion of the specific rates in 100% and 90% ethanol and methanol, a good Grunwald−Winstein plot against YCl values (solvent ionizing power) is obtained, with a slope of 0.47 ± 0.03. The results are compared with those reported earlier for 1-adamantyl chloroformate and isopropyl chloroformate and mechanistic conclusions are drawn.en_US
dc.language.isoen_USen_US
dc.publisherAMER CHEMICAL SOCen_US
dc.titleSolvolysis-Decomposition of 2-Adamantyl Chloroformate: Evidence for Two Reaction Pathwaysen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/jo0207426-
dc.relation.journalJOURNAL OF ORGANIC CHEMISTRY-
dc.contributor.googleauthorKyong, Jin Burm-
dc.contributor.googleauthorYoo, Jung-Suk-
dc.contributor.googleauthorKevill, Dennis N.-
dc.relation.code2009205564-
dc.sector.campusE-
dc.sector.daehakCOLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E]-
dc.sector.departmentDEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING-
dc.identifier.pidjbkyong-


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