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Phase formation and luminescence properties of ternary solid-solution among tetragonal systems

Title
Phase formation and luminescence properties of ternary solid-solution among tetragonal systems
Author
임원빈
Keywords
Solid-state lighting; Photoluminescence; Solid-solution; Ternary system; Rietveld refinement; Phosphor; Yellow emission; White LEDs
Issue Date
2019-08
Publisher
ELSEVIER SCIENCE SA
Citation
JOURNAL OF ALLOYS AND COMPOUNDS, v. 798, Page. 635-643
Abstract
A new strategy for developing solid-solution compounds from three constituent compounds was analyzed. Using this strategy, a series of yellow-light-emitting phosphors derived from ternary solid-solution host compositions were prepared using solid-state synthesis. Three vertex members, Sr3SiO5 (space group P4/ncc), Sr3AlO4F (space group I4/mcm), and LaSr2AlO5 (space group I4/mcm), were selected from similar crystal structures with slightly different symmetries. The crystallization space group of the composition was found to be dependent on the end members, and from the vertex of the ternary plot to the centroid, the composition assumed the space group that was more tolerant toward substitutions. All the compositions, except those lying at the periphery of the ternary plot, formed a single phase and emitted yellow light when activated with Ce3+ ions. The luminescence properties of the 28 selected compositions on the ternary plot were analyzed. The compound that was formed from a 1:2:1 ratio of end members assumed a I4/mcm structure and showed the highest-intensity emission. Phosphor derived from the developed host lattice was analyzed for application in solid-state lighting devices by preparing a white-light emitting device. (C) 2019 Elsevier B.V. All rights reserved.
URI
https://www.sciencedirect.com/science/article/pii/S0925838819320067?via%3Dihubhttps://repository.hanyang.ac.kr/handle/20.500.11754/152566
ISSN
0925-8388; 1873-4669
DOI
10.1016/j.jallcom.2019.05.318
Appears in Collections:
COLLEGE OF ENGINEERING[S](공과대학) > MATERIALS SCIENCE AND ENGINEERING(신소재공학부) > Articles
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