Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | 오창호 | - |
dc.contributor.author | 박란화 | - |
dc.date.accessioned | 2020-02-26T16:30:55Z | - |
dc.date.available | 2020-02-26T16:30:55Z | - |
dc.date.issued | 2014-08 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/129964 | - |
dc.identifier.uri | http://hanyang.dcollection.net/common/orgView/200000424709 | en_US |
dc.description.abstract | Part 1. Gold-Catalyzed Furanyl Cyclopropanation of Acyclic Conjugated Enynone We developed an efficient cascade Au-catalyzed furanylation-cyclopropanation of acyclic enynones which bearing a double bond to the bicyclic compounds. This requires configurational change from the E-isomer to the Z-isomer prior to the furan formation. The intermediate formation was accomplished through 5-exo-dig manner and undergo cyclopropanation of double bond to furnish the product. Part 2. Synthetic Study of Komaroviquinone via Pt-Catalyzed Cyclization In 2010, the seniors in our group reported Pt-catalyzed hydrative cycloaddition of o-alkynylbenzaldehydes with an unsaturated bond and this methology has successfully served as a key step in total synthesis of a natural product faveline methyl ether that has [6.7.6] tricyclic skeleton. Encouraged by this result, we tried another synthetic study of koaroviquinone which was included in icetexane diterpenoid by utilizing pt-catalyzed hydrative cycloaddition as a key step. | - |
dc.publisher | 한양대학교 | - |
dc.title | Gold-Catalyzed Cyclopropanation and the Synthesis of Komaroviquinone via Pt-Catalyzed Cyclization | - |
dc.type | Theses | - |
dc.contributor.googleauthor | 박란화 | - |
dc.contributor.alternativeauthor | Piao, Lanhua | - |
dc.sector.campus | S | - |
dc.sector.daehak | 대학원 | - |
dc.sector.department | 화학과 | - |
dc.description.degree | Doctor | - |
dc.contributor.affiliation | 유기합성 | - |
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