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A facile Synthesis of Polycyclic Spiranes via Pt-Catalyzed cyclization

Title
A facile Synthesis of Polycyclic Spiranes via Pt-Catalyzed cyclization
Other Titles
백금촉매고리화 반응을 이용한 다중고리 Spiranes의 합성
Author
김소영
Advisor(s)
오창호
Issue Date
2015-02
Publisher
한양대학교
Degree
Master
Abstract
Spirane compound has a unique structure and is an important material in pharmaceutical and fine chemistry. We have developed an efficient and novel synthesis of a variety of polycyclic spiranes. The derivatives of 2-(oct-7-en-1-ynyl)benzaldehyde (1) were cycloisomerized into the corresponding cyclopropanes 2 which were isomerized into the corresponding spiranes 3 upon exposure to slight acidic medium such as p-toluenesulfonic acid or heat.
URI
https://repository.hanyang.ac.kr/handle/20.500.11754/128731http://hanyang.dcollection.net/common/orgView/200000425637
Appears in Collections:
GRADUATE SCHOOL[S](대학원) > CHEMISTRY(화학과) > Theses (Master)
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