Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 방진호 | - |
dc.date.accessioned | 2019-12-08T07:07:26Z | - |
dc.date.available | 2019-12-08T07:07:26Z | - |
dc.date.issued | 2018-06 | - |
dc.identifier.citation | JOURNAL OF PHYSICAL CHEMISTRY C, v. 122, no. 25, page. 13267-13276 | en_US |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.jpcc.7b08449 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/118972 | - |
dc.description.abstract | A new nanoarchitecture of cobalt sulfide (CoSx) is designed by exploiting a Prussian blue analogue. Depending on the sulfidation temperatures, CoSx materials with different compositions and morphologies are obtained. This investigation of the composition-dependent electro-catalytic activity of CoSx for triiodide reduction reaction (IRR) reveals that sulfur-deficient CoSx is more active than sulfur-rich CoSx. When utilized in dye-sensitized solar cells (DSSCs), sulfur-deficient CoSx with a hollow nanocube morphology outperforms platinum (Pt), showing great promise as a Pt alternative. This composition dependency on IRR is attributed to different surface characteristics and electrical properties that vary with CoSx composition. This work highlights the importance of understanding the surface properties of sulfide-based electrocatalysts that are intimately dictated by their compositions as part of a new design principle for a highly active electrocatalyst. | en_US |
dc.description.sponsorship | This research was supported by grants from the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT, and Future Planning (NRF-2016R1A1A1A05005038 and 2008-0061891). | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.subject | EFFICIENT COUNTER ELECTRODE | en_US |
dc.subject | METAL-ORGANIC-FRAMEWORKS | en_US |
dc.subject | HYDROGEN EVOLUTION REACTION | en_US |
dc.subject | LITHIUM-ION BATTERIES | en_US |
dc.subject | GRAPHENE OXIDE | en_US |
dc.subject | PLATINUM-ELECTRODE | en_US |
dc.subject | CATALYTIC-ACTIVITY | en_US |
dc.subject | NANOROD ARRAYS | en_US |
dc.subject | REDOX COUPLES | en_US |
dc.subject | COS | en_US |
dc.title | Composition-Dependent Electrocatalytic Activity of Cobalt Sulfides for Triiodide Reduction in Dye-Sensitized Solar Cells | en_US |
dc.type | Article | en_US |
dc.relation.no | 25 | - |
dc.relation.volume | 122 | - |
dc.identifier.doi | 10.1021/acs.jpcc.7b08449 | - |
dc.relation.page | 13267-13276 | - |
dc.relation.journal | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.contributor.googleauthor | Kim, Min Soo | - |
dc.contributor.googleauthor | Bang, Jin Ho | - |
dc.relation.code | 2018001082 | - |
dc.sector.campus | S | - |
dc.sector.daehak | GRADUATE SCHOOL[S] | - |
dc.sector.department | DEPARTMENT OF BIONANOTECHNOLOGY | - |
dc.identifier.pid | jbang | - |
dc.identifier.orcid | https://orcid.org/0000-0002-6717-3454 | - |
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