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Reattachment of crosslinked poly(ethylene oxide) via chain interpenetration and reentanglement induced by a simple wetting process

Title
Reattachment of crosslinked poly(ethylene oxide) via chain interpenetration and reentanglement induced by a simple wetting process
Author
손대원
Keywords
gamma-ray irradiation; Crosslinking; Chain interpenetration; Chain diffusion; Reentanglement; Reattachment
Issue Date
2017-09
Publisher
ELSEVIER SCI LTD
Citation
POLYMER, v. 129, page. 221-227
Abstract
We demonstrate the reattachment of two chemically-crosslinked poly(ethylene oxide) (PEO) matrix samples prepared with the g-ray irradiation method by a simple wetting process with a good solvent. The fractured polymer samples can be attached through chain diffusion, interpenetration into a crosslinked network, and intermixing/reentanglement. Reattached samples exhibit similar macro/microstructure and mechanical properties to those of pristine samples. This effective recovery process without any additional reactive chemicals or external stimuli highlights the importance of extending the use of simple, but fundamental, dynamic behaviors of polymer chains to obtain the desired properties as well as offering a unique and useful route toward effective healable materials. (C) 2017 Elsevier Ltd. All rights reserved.
URI
https://www.sciencedirect.com/science/article/pii/S003238611730914X?via%3Dihubhttps://repository.hanyang.ac.kr/handle/20.500.11754/115479
ISSN
0032-3861; 1873-2291
DOI
10.1016/j.polymer.2017.09.041
Appears in Collections:
COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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