One-Pot Sequential N-Heterocyclic Carbene/Rhodium(III) Catalysis: Synthesis of Fused Polycyclic Isocoumarins
- Title
- One-Pot Sequential N-Heterocyclic Carbene/Rhodium(III) Catalysis: Synthesis of Fused Polycyclic Isocoumarins
- Author
- 윤소원
- Keywords
- benzo-fused lactones; C-H activation; one-pot sequential catalysis; organocatalysis; rhodium catalysis
- Issue Date
- 2017-07
- Publisher
- WILEY-V C H VERLAG GMBH
- Citation
- ADVANCED SYNTHESIS & CATALYSIS, v. 359, no. 13, page. 2176-2183
- Abstract
- A one-pot sequential N-heterocyclic carbene-rhodium (NHC-Rh) catalysis is described, demonstrating the compatibility of NHC and Rh catalysts. N-Heterocyclic carbene-catalyzed aerobic oxidation of benzaldehydes and subsequent rhodium(III)-catalyzed oxidative coupling/ annulation with multiple bonds enabled the formation of two C-O bonds and one C-C bond in a single pot. This operationally easy, one-pot protocol under air provides access to a diverse array of valuable fused polycyclic isocoumarins.
- URI
- https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201700072https://repository.hanyang.ac.kr/handle/20.500.11754/114903
- ISSN
- 1615-4150; 1615-4169
- DOI
- 10.1002/adsc.201700072
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
- Files in This Item:
There are no files associated with this item.
- Export
- RIS (EndNote)
- XLS (Excel)
- XML