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Quantitative Correlation between Carrier Mobility and Intermolecular Center-to-Center Distance in Organic Single Crystals

Title
Quantitative Correlation between Carrier Mobility and Intermolecular Center-to-Center Distance in Organic Single Crystals
Author
이상욱
Keywords
FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; STRUCTURE-PROPERTY RELATIONSHIPS; CHARGE-TRANSPORT; LATTICE STRAIN; SEMICONDUCTORS; PERFORMANCE; PARAMETERS; MORPHOLOGY; PENTACENE
Issue Date
2017-05
Publisher
AMER CHEMICAL SOC
Citation
CHEMISTRY OF MATERIALS, v. 29, no. 9, page. 4072-4079
Abstract
Charge transport properties of organic semiconductors critically depend on their molecular packing structures. Controlling the charge transport by varying the molecular packing and understanding their structure property correlations are essential for developing high-performance organic electronic devices. Here, we demonstrate that the charge carrier mobility in organic single-crystal nanowires can be modulated with respect to the intermolecular center-to-center distance by applying uniaxial strain to the cofacially stacked crystals. Monotonic changes in charge carrier mobility (from 0.0196 to 19.6 cm(2)V(-1)s(-1) for 6,13-bis(triisopropylsilylethylnyl) pentacene (TIPS-PEN)) were observed under a wide range of strains from 16.7% (compressive) to 16.7% (tensile). Furthermore, the measured values of charge carrier mobility were in good agreement with theoretical calculations based on charge localized hopping theory. These results provide a definitive relationship between intermolecular packing arrangement and charge transports, which enables a huge improvement in charge carrier mobility for organic single-crystal materials.
URI
https://pubs.acs.org/doi/10.1021/acs.chemmater.7b00827https://repository.hanyang.ac.kr/handle/20.500.11754/114081
ISSN
0897-4756; 1520-5002
DOI
10.1021/acs.chemmater.7b00827
Appears in Collections:
GRADUATE SCHOOL[S](대학원) > BIONANOTECHNOLOGY(바이오나노학과) > Articles
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