Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김종만 | - |
dc.date.accessioned | 2019-10-31T00:34:54Z | - |
dc.date.available | 2019-10-31T00:34:54Z | - |
dc.date.issued | 2019-05 | - |
dc.identifier.citation | ACS MACRO LETTERS, v. 8, NO 5, Page. 610-615 | en_US |
dc.identifier.issn | 2161-1653 | - |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acsmacrolett.9b00169 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/111680 | - |
dc.description.abstract | The cation-directed self-assembly process has emerged as a fascinating approach for constructing supra molecular architectures and manifested a diverse range of assembly related applications. Herein, we synthesized a macrocyclic structure containing bis-amidopyridine and photopolymerizable diacetylene template, PyMCDA. Owing to the metal coordination affinity of bis-amidopyridine and the pi-pi stacking characteristic of diacetylene template and complementary to the cyclic molecular framework, Cs+-directed organic nanotubes are generated via unidirectional self assembly of PyMCDA. The monomeric PyMCDA nanotubes are transformed into the covalently cross-linked chromogenic polydiacetylene nanotubes (PyMCPDA-Cs+) by UV-promoted topochemical polymerization. The result of a metal ligand coordination characteristic, geometric parameters in solid-state assemblies, and topochemical polymerization behavior reveals a generation of Cs+ ion inserted nanotubes. Interestingly, PyMCDA-Cs+ nanotubes display thermochromic property with a brilliant blue-to-red color transition. | en_US |
dc.description.sponsorship | The authors thank the National Research Foundation of Korea for financial support (NRF-2017R1A2A1A05000752). | en_US |
dc.language.iso | en | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.subject | TOPOCHEMICAL POLYMERIZATION | en_US |
dc.subject | RECENT PROGRESS | en_US |
dc.subject | TEMPERATURE | en_US |
dc.subject | PHOTOPOLYMERIZATION | en_US |
dc.subject | DESIGN | en_US |
dc.title | Cation-Directed Self-Assembly of Macrocyclic Diacetylene for Developing Chromogenic Polydiacetylene | en_US |
dc.type | Article | en_US |
dc.relation.no | 5 | - |
dc.relation.volume | 8 | - |
dc.identifier.doi | 10.1021/acsmacrolett.9b00169 | - |
dc.relation.page | 610-615 | - |
dc.relation.journal | ACS MACRO LETTERS | - |
dc.contributor.googleauthor | Shin, Geon | - |
dc.contributor.googleauthor | Khazi, Mohammed Iqbal | - |
dc.contributor.googleauthor | Kundapur, Umesha | - |
dc.contributor.googleauthor | Kim, Bubsung | - |
dc.contributor.googleauthor | Kim, Youngmee | - |
dc.contributor.googleauthor | Lee, Chan Woo | - |
dc.contributor.googleauthor | Kim, Jong-Man | - |
dc.relation.code | 2019000447 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF ENGINEERING[S] | - |
dc.sector.department | DEPARTMENT OF CHEMICAL ENGINEERING | - |
dc.identifier.pid | jmk | - |
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