Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 나명수 | - |
dc.date.accessioned | 2019-09-04T05:46:18Z | - |
dc.date.available | 2019-09-04T05:46:18Z | - |
dc.date.issued | 2005-02 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v. 44, No. 6, Page. 1934-1940 | en_US |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.issn | 1520-510X | - |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/ic0486872 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/110195 | - |
dc.description.abstract | By modulating the secondary building units derived from the primary building units, N-acylsalicylhydrazides (H-3-xshz), we have been able to construct isostructural but tunable host networks, [Mn-6(xshZ)(6)(dmf)(2)(bpea)(2)], with different cavity sizes and shapes where the secondary building units, [Mn-6(xshz)(6)], were linked through exo-bidentate bridging ligand, 1,2-bis(pyridyl)ethane (bpea) to form 3-D networks. With a short length linear N-acyl side chain at the primary building unit, the host networks have a 3-D network with three-dimensional cavities. With an appropriate length linear N-acyl side chain at the primary building unit, the host network keeps the isostructural 3-D network but with two types of one-dimensional channels of reduced cavity volume. The tuned host networks showed not only size selectivity for the guest molecules but also shape selectivity. While the three-dimensional channeled host showed selectivity depending on the length of the podal guests, the one-dimensional channeled host showed selectivity depending on both the length and/or the podality of the guest molecules. | en_US |
dc.description.sponsorship | We thank the Korean Institute of Basic Science for elemental analyses. The authors wish to acknowledge the financial support of KISTEP (M1-0213-03-0004) and CBMH. | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.title | Size and Shape Selectivity of Host Networks Built Based on Tunable Secondary Building Units | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1021/ic0486872 | - |
dc.relation.journal | INORGANIC CHEMISTRY | - |
dc.contributor.googleauthor | Moon, D | - |
dc.contributor.googleauthor | Lah, MS | - |
dc.relation.code | 2009204045 | - |
dc.sector.campus | E | - |
dc.sector.daehak | COLLEGE OF SCIENCE & TECHNOLOGY[E] | - |
dc.sector.department | DIVISION OF SCIENCE & TECHNOLOGY | - |
dc.identifier.pid | mslah | - |
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