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dc.contributor.author윤소원-
dc.date.accessioned2019-08-12T05:18:24Z-
dc.date.available2019-08-12T05:18:24Z-
dc.date.issued2019-02-
dc.identifier.citationADVANCED SYNTHESIS & CATALYSIS, v. 361, NO 3, Page. 462-468en_US
dc.identifier.issn1615-4150-
dc.identifier.issn1615-4169-
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201801265-
dc.identifier.urihttps://repository.hanyang.ac.kr/handle/20.500.11754/108475-
dc.description.abstractA palladium-catalyzed aerobic C-H amidation of N-Ts-2-amino-3 '-hydroxylbiaryls has been developed to afford a diverse range of 1-hydroxycarbazoles with high regioselectivity and efficiency. This protocol benefits from operational simplicity, robustness, and sustainability with the use of ambient air as the sole terminal oxidant. Further elaboration of the products obtained from this process provides facile access to various carbazole alkaloids including carbazolequinones and biscarbazoles. A mechanism involving dual directing group-assisted regioselective C-H activation at the more sterically hindered C2 '-position of 2-amino-3 '-hydroxylbiaryls is proposed.en_US
dc.description.sponsorshipThis work was supported by both Basic Science Research Program and Nano.Material Technology Department Program through the National Research Foundation of Korea (NRF) funded by the Korea government (MSIP) (Nos. 2012M3A7B4049644, 2014-011165, 2015R1A2A2A01002559, and 2018R1A2A2A05018392).en_US
dc.language.isoenen_US
dc.publisherWILEY-V C H VERLAG GMBHen_US
dc.subjectcarbazolesen_US
dc.subjectC-H activationen_US
dc.subjectpalladium catalysisen_US
dc.subjectregioselectivityen_US
dc.titlePalladium-Catalyzed Regioselective Synthesis of 1-Hydroxycarbazoles Under Aerobic Conditionsen_US
dc.typeArticleen_US
dc.relation.no3-
dc.relation.volume361-
dc.identifier.doi10.1002/adsc.201801265-
dc.relation.page462-468-
dc.relation.journalADVANCED SYNTHESIS & CATALYSIS-
dc.contributor.googleauthorYoun, So Won-
dc.contributor.googleauthorKim, Young Ho-
dc.contributor.googleauthorJo, Yoon Hyung-
dc.relation.code2019002950-
dc.sector.campusS-
dc.sector.daehakCOLLEGE OF NATURAL SCIENCES[S]-
dc.sector.departmentDEPARTMENT OF CHEMISTRY-
dc.identifier.pidsowony73-
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COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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