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Thermomechanical properties and shape memory effect of epoxidized natural rubber crosslinked by 3-amino-1,2,4-triazole

Title
Thermomechanical properties and shape memory effect of epoxidized natural rubber crosslinked by 3-amino-1,2,4-triazole
Author
김동국
Keywords
epoxidized natural rubber (ENR); 3-amino-1,2,4-triazole (ATA); thermomechanical properties; shape memory effect
Issue Date
2007-12
Publisher
JOHN WILEY & SONS LTD
Citation
POLYMER INTERNATIONAL, v. 56, No. 5, Page. 694-698
Abstract
A thermally induced shape memory polymer based on epoxidized natural rubber (ENR) was produced by curing the ENR with 3-amino-1,2,4-triazole as a crosslinker in the presence of bisphenol-A as a catalyst. Dynamic mechanical and tensile analysis was conducted to examine the variation of glass transition temperature, stiffness, and extensibility of the vulcanizates with the amount of curatives. Shape memory properties of the ENR vulcanizates were characterized by shape retention and shape recovery. It was revealed that the glass transition temperature of the ENR vulcanizates could be tuned well above room temperature by increasing the amount of curing agents. Also, ENR vulcanizates with T-g higher than ambient temperature showed good shape memory effects under 100% elongation, and the response temperatures of the recovery were well matched with T-g of the samples. (C) 2006 Society of Chemical Industry.
URI
https://onlinelibrary.wiley.com/doi/full/10.1002/pi.2203https://repository.hanyang.ac.kr/handle/20.500.11754/107495
ISSN
0959-8103
DOI
10.1002/pi.2203
Appears in Collections:
COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > CHEMICAL AND MOLECULAR ENGINEERING(화학분자공학과) > Articles
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