Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 나명수 | - |
dc.date.accessioned | 2019-07-10T07:13:48Z | - |
dc.date.available | 2019-07-10T07:13:48Z | - |
dc.date.issued | 2007-11 | - |
dc.identifier.citation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v. 28, No. 11, Page. 2009-2014 | en_US |
dc.identifier.issn | 1229-5949 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | http://www.koreascience.or.kr/article/JAKO200702727291444.page | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/107283 | - |
dc.description.abstract | The aminolysis of diphenyl thiophosphinic chloride (2) with substituted anilines in acetonitrile at 55.0 oC is investigated kinetically. Kinetic results yield large Hammett ρX (ρnuc = ?3.97) and Bronsted βX (βnuc = 1.40) values. A concerted mechanism involving a partial frontside nucleophilic attack through a hydrogen-bonded, four-center type transition state is proposed on the basis of the primary normal kinetic isotope effects (kH/kD = 1.0-1.1) with deuterated aniline (XC6H4ND2) nucleophiles. The natural bond order charges on P and the degrees of distortion of 42 compounds: chlorophosphates [(R1O)(R2O)P(=O)Cl], chlorothiophosphates [(R1O)(R2O)P(=S)Cl], phosphonochloridates [(R1O)R2P(=O)Cl], phosphonochlorothioates [(R1O)R2P(=S)Cl], chlorophosphinates [R1R2P(=O)Cl], and chlorothiophosphinates [R1R2P(=S)Cl] are calculated at the B3LYP/ 6-311+G(d,p) level in the gas phase. | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | KOREAN CHEMICAL SOC | en_US |
dc.subject | self-assembly | en_US |
dc.subject | molecular polygon | en_US |
dc.subject | octanuclear metallamacrocycle | en_US |
dc.subject | dodecanuclear metallamacrocycle | en_US |
dc.subject | solvent effect | en_US |
dc.title | Solvent Effect on the Nature of the Metallamacrocycles formed: Formation of Octanuclear and Dodecanuclear Manganese Metalladiazamacrocycles | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.5012/bkcs.2007.28.11.2009 | - |
dc.relation.journal | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.contributor.googleauthor | John, Rohith P. | - |
dc.contributor.googleauthor | Lee, Kyungjin | - |
dc.contributor.googleauthor | Lee, Kyungjae | - |
dc.contributor.googleauthor | Park, Mira | - |
dc.contributor.googleauthor | Lah, Myoung Soo | - |
dc.relation.code | 2007214307 | - |
dc.sector.campus | E | - |
dc.sector.daehak | COLLEGE OF SCIENCE & TECHNOLOGY[E] | - |
dc.sector.department | DIVISION OF SCIENCE & TECHNOLOGY | - |
dc.identifier.pid | mslah | - |
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