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A Chiral Pentadecanuclear Metallamacrocycle with a Sextuple Twisted Möbius Topology

Title
A Chiral Pentadecanuclear Metallamacrocycle with a Sextuple Twisted Möbius Topology
Author
나명수
Keywords
CHEMISTRY; METALLADIAZAMACROCYCLE; NUCLEARITY; MOLECULES; CRYSTALS
Issue Date
2007-11
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v. 129, No. 46, Page. 14142-14143
Abstract
A C (3) symmetric pentadecanuclear metallamacrocycle was obtained by the self-assembly of a pentadentate bridging ligand, N -phenylpropiolyl salicylhydrazide (H3L), and a manganese ion. The combination of a narrow C alpha-C beta region near the bridging domain and a bulky phenyl end away from the bridging domain as a steric domain induced clockwise twists in the cycle. The resulting macrocycle with a sextuple twisted Mobius topology was stabilized by extensive weak intramolecular interactions.
URI
https://pubs.acs.org/doi/abs/10.1021/ja075945whttps://repository.hanyang.ac.kr/handle/20.500.11754/107274
ISSN
0002-7863
DOI
10.1021/ja075945w
Appears in Collections:
COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > ETC
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