A Chiral Pentadecanuclear Metallamacrocycle with a Sextuple Twisted Möbius Topology
- Title
- A Chiral Pentadecanuclear Metallamacrocycle with a Sextuple Twisted Möbius Topology
- Author
- 나명수
- Keywords
- CHEMISTRY; METALLADIAZAMACROCYCLE; NUCLEARITY; MOLECULES; CRYSTALS
- Issue Date
- 2007-11
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v. 129, No. 46, Page. 14142-14143
- Abstract
- A C (3) symmetric pentadecanuclear metallamacrocycle was obtained by the self-assembly of a pentadentate bridging ligand, N -phenylpropiolyl salicylhydrazide (H3L), and a manganese ion. The combination of a narrow C alpha-C beta region near the bridging domain and a bulky phenyl end away from the bridging domain as a steric domain induced clockwise twists in the cycle. The resulting macrocycle with a sextuple twisted Mobius topology was stabilized by extensive weak intramolecular interactions.
- URI
- https://pubs.acs.org/doi/abs/10.1021/ja075945whttps://repository.hanyang.ac.kr/handle/20.500.11754/107274
- ISSN
- 0002-7863
- DOI
- 10.1021/ja075945w
- Appears in Collections:
- COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > ETC
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