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dc.contributor.author경진범-
dc.date.accessioned2019-06-12T04:46:24Z-
dc.date.available2019-06-12T04:46:24Z-
dc.date.issued2007-05-
dc.identifier.citationJOURNAL OF PHYSICAL ORGANIC CHEMISTRY, v. 20, No. 7, Page. 525-531en_US
dc.identifier.issn0894-3230-
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/abs/10.1002/poc.1194-
dc.identifier.urihttps://repository.hanyang.ac.kr/handle/20.500.11754/106492-
dc.description.abstractThe specific rates of solvolysis of 2-adamantyl fluoroformate have been measured at 25.0 degrees C in 20 pure and binary solvents. These are well correlated using the extended Grunwald-Winstein equation, with incorporation of the NT solvent nucleophilicity scale and the Y-Cl solvent ionizing power scale. The sensitivities (l = 2.15 +/- 0.17 and m = 0.95 +/- 0.07) toward the changes in solvent nucleophilicity and solvent ionizing power, and the k(F)/k(Cl) values are very similar to those previously observed for solvolyses of n-octyl fluoroformate, consistent with the addition step of an addition-elimination pathway being rate-determining. For aqueous ethanol, measurement of the product ratio allowed selectivity values (S) to be determined. The results are compared with those reported earlier for 2-adamantyl chloroformate and mechanistic conclusions are drawn. Copyright (c) 2007 John Wiley & Sons, Ltd.en_US
dc.language.isoen_USen_US
dc.publisherJOHN WILEY & SONS LTDen_US
dc.subject2-adamantyl fluoroformateen_US
dc.subjectaddition-eliminationen_US
dc.subjectGrunwald-Winstein equationen_US
dc.subjectproduct selectivityen_US
dc.titleRate and Product Studies with 2-Adamantyl Fluoroformate under Solvolytic Conditionsen_US
dc.typeArticleen_US
dc.identifier.doi10.1002/poc.1194-
dc.relation.journalJOURNAL OF PHYSICAL ORGANIC CHEMISTRY-
dc.contributor.googleauthorKyong, Jin Burm-
dc.contributor.googleauthorRhu, Chan Joo-
dc.contributor.googleauthorKim, Yong-Gun-
dc.contributor.googleauthorKevill, Dennis N.-
dc.relation.code2007205644-
dc.sector.campusE-
dc.sector.daehakEXECUTIVE VICE PRESIDENT (ERICA)[E]-
dc.sector.departmentHANYANG INSTITUTE FOR TALENT DEVELOPMENT-
dc.identifier.pidjbkyong-
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