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Zirconium-Formate Macrocycles and Supercage: Molecular Packing versus MOF-like Network for Water Vapor Sorption

Title
Zirconium-Formate Macrocycles and Supercage: Molecular Packing versus MOF-like Network for Water Vapor Sorption
Author
전형필
Keywords
METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE; SURFACE-AREA; STABILITY; CLUSTERS; STORAGE; ADSORPTION; CHEMISTRY; CRYSTALS; CAPTURE
Issue Date
2018-08
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v. 140, No. 34, Page. 10915-10920
Abstract
In systematic efforts toward a new type of molecule-based porous materials, facile and efficient synthetic methods have been established to obtain macrocyclic [Zr-6](6) and supercage-like {[Zr-6](6)}(8), where [Zr-6] represents [Zr6O4(OH)(4)(CO2)] building unit commonly found in Zr-based metal organic frameworks. The reactions involve in situ hydrolysis of DMF solvent to produce formate linkers and thus do not require any organic ligand. A minor variation in the composition of two cyclic hexamers thus obtained results in dramatic differences in crystal packing which in turn lead to distinctive and selective sorption behavior for water vapor. It is shown that the high heat of water adsorption and unrestricted uptake under high humidity are consequences of the highly polar surface and flexible crystal packing. The reversibility of water adsorption is demonstrated by cyclic measurements of uptake and regeneration under dynamic flow conditions.
URI
https://pubs.acs.org/doi/abs/10.1021/jacs.8b06757https://repository.hanyang.ac.kr/handle/20.500.11754/105672
ISSN
0002-7863
DOI
10.1021/jacs.8b06757
Appears in Collections:
COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E](과학기술융합대학) > CHEMICAL AND MOLECULAR ENGINEERING(화학분자공학과) > Articles
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