Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김용신 | - |
dc.date.accessioned | 2019-05-10T06:07:28Z | - |
dc.date.available | 2019-05-10T06:07:28Z | - |
dc.date.issued | 2017-12 | - |
dc.identifier.citation | CHEMISTRYSELECT, v. 2, No. 35, Page. 11487-11491 | en_US |
dc.identifier.issn | 2365-6549 | - |
dc.identifier.uri | https://onlinelibrary.wiley.com/doi/abs/10.1002/slct.201702085 | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/103842 | - |
dc.description.abstract | We synthesised aza-12-crown-4 ether-substituted naphthalene diimide (NDI-12-C-4) and demonstrated its properties as an fluorescent and colorimetric sensor. The NDI-12-C-4 uses the aza-12-crown-4 moiety to bind Li+ ion selectively over larger monovalent cation such as Cs+, Na+ and K+. The sensor is chemically stable due to the crown-ether, and the appended NDI fluorophore allows leads to optical changes exclusively for the monovalent Li+ ion. UV-vis absorption, fluorescence, cyclic voltammetry (CV), 1HNMR and naked eye-detection clearly demonstrate selective, sensitive binding of Li+ ion with a detection limit of 5.0 mu M. Importantly, reversible binding of Li+ by NDI-12-C-4 was also observed upon addition of EDTA, after which the sensor could be recovered via simple centrifugation, indicating suitability for use in a biological sensor device. | en_US |
dc.description.sponsorship | D.D.L. thanks RMIT University and Program 165 for financial support. S.V.B. acknowledges the Australian Research Council under a Future Fellowship Scheme (FT110100152). The authors acknowledge the facilities, and the scientific and technical assistance, of the Australian Microscopy & Microanalysis Research Facility (RMMF) at RMIT University. | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | WILEY-V C H VERLAG GMBH | en_US |
dc.subject | aza-12-crown-4 | en_US |
dc.subject | Li sensing | en_US |
dc.subject | naphthalene diimide | en_US |
dc.subject | optical and electrochemical probe | en_US |
dc.subject | selective for monovalent cation | en_US |
dc.title | An Aza-12-crown-4 Ether-Substituted Naphthalene Diimide Chemosensor for the Detection of Lithium Ion | en_US |
dc.type | Article | en_US |
dc.relation.no | 35 | - |
dc.relation.volume | 2 | - |
dc.identifier.doi | 10.1002/slct.201702085 | - |
dc.relation.page | 11487-11491 | - |
dc.relation.journal | CHEMISTRYSELECT | - |
dc.contributor.googleauthor | Hangarge, Rahul V | - |
dc.contributor.googleauthor | La, Duong Duc | - |
dc.contributor.googleauthor | Boguslavsky, Miron | - |
dc.contributor.googleauthor | Jones, Lathe A | - |
dc.contributor.googleauthor | Kim, Yong Shin | - |
dc.contributor.googleauthor | Bhosale, Sheshanath V | - |
dc.relation.code | 2017042722 | - |
dc.sector.campus | E | - |
dc.sector.daehak | COLLEGE OF SCIENCE AND CONVERGENCE TECHNOLOGY[E] | - |
dc.sector.department | DEPARTMENT OF CHEMICAL AND MOLECULAR ENGINEERING | - |
dc.identifier.pid | yongshin | - |
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