TY - JOUR AU - 선양국 DA - 2016/01 PY - 2016 UR - http://onlinelibrary.wiley.com/doi/10.1002/aenm.201501480/abstract;jsessionid=7E80CB0DA5E275557FFD27902492B9BA.f03t02 UR - http://hdl.handle.net/20.500.11754/30598 AB - A novel nanocomposite cathode consisting of sulfur and hollow-mesoporous titania (HMT) embedded within carbon nanotubes (CNT), which is designated as S-HMT@CNT, has been obtained by encapsulating elemental sulfur into the pores of hollow-mesoporous, spherical TiO2 particles that are connected via CNT. A carbon-paper interlayer, referred to as dual functional porous carbon wall (DF-PCW), has been obtained by filling the voids in TiO2 spheres with carbon and then etching the TiO2 template with a chemical process. The DF-PCW interlayer provides a medium for scavenging the lithium polysulfides and suppressing them from diffusing to the anode side when it is inserted between the sulfur cathode and the separator. Lithium-sulfur cells fabricated with the thus prepared S-HMT@CNT cathode and the DF-PCW interlayer exhibit superior performance due to the containment of sulfur in TiO2 and improved lithium-ion and electron transports. The Li-S cells display high capacity with excellent capacity retention at rates as high as 1C, 2C, and 5C rates. PB - WILEY-V C H VERLAG GMBH KW - LI-S BATTERIES KW - COMPOSITE CATHODE MATERIALS KW - REDUCED GRAPHENE OXIDE KW - ION BATTERIES KW - POLYPYRROLE COMPOSITE KW - PERFORMANCE KW - CELLS KW - ANODE KW - CYCLABILITY KW - ELECTRODE TI - High-Energy, High-Rate, Lithium-Sulfur Batteries: Synergetic Effect of Hollow TiO2-Webbed Carbon Nanotubes and a Dual Functional Carbon-Paper Interlayer IS - 1 VL - 6 DO - 10.1002/aenm.201501480 T2 - ADVANCED ENERGY MATERIALS ER -