Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 윤소원 | - |
dc.date.accessioned | 2018-07-26T01:58:51Z | - |
dc.date.available | 2018-07-26T01:58:51Z | - |
dc.date.issued | 2012-07 | - |
dc.identifier.citation | Journal of the American Chemical Society, 2012, 134(28), P.11308-11311 | en_US |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/ja304616q | - |
dc.identifier.uri | https://repository.hanyang.ac.kr/handle/20.500.11754/73033 | - |
dc.description.abstract | A Pd(II)-catalyzed reaction engaging alkenyl beta-keto esters is reported that leads to the formation of 1-naphthols and an unexpected generation of arylpalladium-(II) species. Interception of the in situ generated arylpalladium(II) species in a Mizoroki-Heck reaction, together with additional mechanistic studies, provided strong evidence in support of the first aromatization-driven beta-carbon elimination process. A single Pd catalyst served to promote a series of both C-C bond forming and cleavage events in an unprecedented manner. | en_US |
dc.description.sponsorship | This work was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (Nos. 2011-0003705 and 2012-0002223). We sincerely thank Professor David Yu-Kai Chen (Department of Chemistry, Seoul National University) for helpful discussions and valuable suggestions as well as editorial assistance. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Amer Chemical SOC | en_US |
dc.title | Pd-Catalyzed Sequential C-C Bond Formation and Cleavage: Evidence for an Unexpected Generation of Arylpalladium(II) Species | en_US |
dc.type | Article | en_US |
dc.relation.no | 28 | - |
dc.relation.volume | 134 | - |
dc.identifier.doi | 10.1021/ja304616q | - |
dc.relation.page | 11308-11311 | - |
dc.relation.journal | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.contributor.googleauthor | Youn, S.W. | - |
dc.contributor.googleauthor | Kim, B.S. | - |
dc.contributor.googleauthor | Jagdale, A.R. | - |
dc.relation.code | 2012205895 | - |
dc.sector.campus | S | - |
dc.sector.daehak | COLLEGE OF NATURAL SCIENCES[S] | - |
dc.sector.department | DEPARTMENT OF CHEMISTRY | - |
dc.identifier.pid | sowony73 | - |
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