Chemical synthesis and electrochemical analysis of nickel cobaltite nanostructures for supercapacitor applications

Title
Chemical synthesis and electrochemical analysis of nickel cobaltite nanostructures for supercapacitor applications
Authors
한성환
Keywords
Oxide materials; Thin films; Chemical synthesis; Supercapacitor
Issue Date
2011-12
Publisher
Elsevier Science B.V., Amsterdam.
Citation
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509(23), P.6677-6682
Abstract
Nickel cobaltite (NiCo2O4) films containing nanorods and nanoflakes are synthesized on indium tin oxide (ITO) substrates by a chemical bath deposition method and calcination process at 300 °C for 3 h. The NiCo2O4/ITO films are used as electrodes for supercapacitor applications, and electrochemical properties of the NiCo2O4 nanostructures are examined by cyclic voltammetry and charge–discharge experiments. NiCo2O4 nanorods exhibit the largest specific capacitance, with a value of 490 F g−1at energy and power densities of 45 Wh kg−1 and 2 kW kg−1, respectively. This is significantly better than the performance of NiCo2O4 nanoflakes. Cycle-life tests show that the specific capacitance of NiCo2O4 is stable even after 1000 cycles, indicating its high potential for supercapacitor applications. The low cost and environmental friendliness of NiCo2O4 nanorods, coupled with its high supercapacitor performance, offer advantages over other transition metal oxides used for supercapacitors.
URI
https://www.sciencedirect.com/science/article/pii/S0925838811007559http://hdl.handle.net/20.500.11754/66818
ISSN
0925-8388
DOI
http://dx.doi.org/10.1016/j.jallcom.2011.03.136
Appears in Collections:
COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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