38 0

Trifluoromethylation of Alkenes by Visible Light Photoredox Catalysis

Title
Trifluoromethylation of Alkenes by Visible Light Photoredox Catalysis
Author
조은진
Keywords
Alkenes; chemistry; Catalysis; Chlorofluorocarbons; Methane; Light; Oxidation-Reduction; Photochemical Processes
Issue Date
2012-12
Publisher
AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Citation
Journal of organic chemistry, v.77, no.24, pp.11383-11387
Abstract
A method for trifluoromethylation of alkenes has been developed employing visible light photoredox catalysis with CF3I, Ru(Phen)(3)Cl-2, and DBU. This process works especially well for terminal alkenes to give alkenyl-CF3 products with only E-stereochemistry. The mild reaction conditions enable the trifluoromethylation of a range of alkenes that bear various functional groups.
URI
http://pubs.acs.org/doi/abs/10.1021%2Fjo3022346http://hdl.handle.net/20.500.11754/54354
ISSN
0022-3263
DOI
10.1021/jo3022346
Appears in Collections:
GRADUATE SCHOOL[S](대학원) > BIONANOTECHNOLOGY(바이오나노학과) > Articles
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE