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Trifluoromethylation of Alkenes by Visible Light Photoredox Catalysis
- Title
- Trifluoromethylation of Alkenes by Visible Light Photoredox Catalysis
- Author
- 조은진
- Keywords
- Alkenes; chemistry; Catalysis; Chlorofluorocarbons; Methane; Light; Oxidation-Reduction; Photochemical Processes
- Issue Date
- 2012-12
- Publisher
- AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
- Citation
- Journal of organic chemistry, v.77, no.24, pp.11383-11387
- Abstract
- A method for trifluoromethylation of alkenes has been developed employing visible light photoredox catalysis with CF3I, Ru(Phen)(3)Cl-2, and DBU. This process works especially well for terminal alkenes to give alkenyl-CF3 products with only E-stereochemistry. The mild reaction conditions enable the trifluoromethylation of a range of alkenes that bear various functional groups.
- ISSN
- 0022-3263
- Appears in Collections:
- GRADUATE SCHOOL[S](대학원) > BIONANOTECHNOLOGY(바이오나노학과) > Articles
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