Repository at Hanyang UniversityGRADUATE SCHOOL[S](대학원)BIONANOTECHNOLOGY(바이오나노학과)Articles
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dc.contributor.author조은진-
dc.date.accessioned2018-03-26T08:59:46Z-
dc.date.available2018-03-26T08:59:46Z-
dc.date.issued2014-09-
dc.identifier.citationPhotocatalysis in Organic Synthesis, 2014, 356(13), P.2741-2748en_US
dc.identifier.issn1615-4150-
dc.identifier.issn1615-4169-
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201400542-
dc.identifier.urihttp://hdl.handle.net/20.500.11754/52705-
dc.description.abstractDifluoroalkylated aromatics are important structural motifs in pharmaceutical and agrochemical applications. Herein, we report their synthesis by a mild, efficient, and convenient method using visible light photoredox catalysis. A variety of unactivated aromatics were difluoroalkylated with ethyl 2?bromo?2,2?difluoroacetate (BrCF2CO2Et) in the presence of the triscyclometalated Ir complex fac?[Ir(ppy)3] under visible light irradiation at room temperature. It is shown that reaction outcomes containing the CF2CO2Et moiety can be converted to a variety of other CF2?containing aromatics, demonstrating the synthetic utility of the present method.en_US
dc.description.sponsorshipThis work was supported by the National Research Founda-tion of Korea (NRF) [NRF-2014R1A1A1A05003274, NRF-2014-011165, and NRF-012M3A7B4049657 (Nano MaterialTechnology Develop ment Program)] and the TJ Science Fel-lowship of the POSCO TJ Park Foundation.en_US
dc.language.isoenen_US
dc.publisherWILEY-V C H VERLAG GMBHen_US
dc.subjectaromaticsen_US
dc.subjectdifluoroalkylationen_US
dc.subjectheteroaromaticsen_US
dc.subjectiridiumen_US
dc.subjectvisible lighten_US
dc.subjectCOPPER-MEDIATED DIFLUOROMETHYLATIONen_US
dc.subjectC-H ACTIVATIONen_US
dc.subjectPHOTOREDOX CATALYSISen_US
dc.subjectF BONDen_US
dc.subjectTRIFLUOROMETHYLATIONen_US
dc.subjectHETEROARENESen_US
dc.subjectIODIDESen_US
dc.subjectALKENESen_US
dc.subjectARYLen_US
dc.subjectPERFLUOROALKYLATIONen_US
dc.titleVisible Light-Induced Aromatic Difluoroalkylationen_US
dc.typeArticleen_US
dc.relation.no13-
dc.relation.volume356-
dc.identifier.doi10.1002/adsc.201400542-
dc.relation.page2741-2748-
dc.relation.journalADVANCED SYNTHESIS & CATALYSIS-
dc.contributor.googleauthorJung, Jaehun-
dc.contributor.googleauthorKim, Eunjin-
dc.contributor.googleauthorYou, Youngmin-
dc.contributor.googleauthorCho, Eun Jin-
dc.relation.code2014024260-
dc.sector.campusS-
dc.sector.daehakGRADUATE SCHOOL[S]-
dc.sector.departmentDEPARTMENT OF BIONANOTECHNOLOGY-
dc.identifier.pidecho-
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