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Total Synthesis of (+/-)-Lycorine from the Endo-Cycloadduct of 3,5-Dibromo-2-pyrone and (E)-beta-Borylstyrene
- Title
- Total Synthesis of (+/-)-Lycorine from the Endo-Cycloadduct of 3,5-Dibromo-2-pyrone and (E)-beta-Borylstyrene
- Other Titles
- -)-Lycorine from the Endo-Cycloadduct of 3,5-Dibromo-2-pyrone and (E)-beta-Borylstyrene
- Author
- 조천규
- Keywords
- Amaryllidaceae Alkaloids; chemical synthesis; Molecular Structure; Oxidation-Reduction; Phenanthridines; Pyrones; chemistry; Stereoisomerism; Styrenes
- Issue Date
- 2014-09
- Publisher
- American Chemical Society
- Citation
- Organic Letters, 2014, 16(21), P.5718-5720
- Abstract
- A new synthetic route to (±)-lycorine, starting from the endo-cycloadduct of 3,5-dibromo-2-pyrone and (E)-β-borylstyrene, is reported. Boronate oxidation and a set of reactions including face-selective epoxidation provided the pivotal C1-OH group and C3/C3a double bond.
- ISSN
- 1523-7060; 1523-7052
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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