Comparison of Nanorod-Structured Li[Ni0.54Co0.16Mn0.30]O2 with Conventional Cathode Materials for Li-Ion Batteries

Title
Comparison of Nanorod-Structured Li[Ni0.54Co0.16Mn0.30]O2 with Conventional Cathode Materials for Li-Ion Batteries
Author
선양국
Keywords
cathode materials; electrochemistry; full concentration gradient; lithium; nanostructures
Issue Date
2014-01
Publisher
WILEY-V C H VERLAG GMBH
Citation
CHEMSUSCHEM; JAN 2014, 7, 1, p245-p252
Abstract
We successfully synthesized a safe, high-capacity cathode material specifically engineered for EV applications with a full concentration gradient (FCG) of Ni and Co ions at a fixed Mn content throughout the particles. The electrochemical and thermal properties of the FCG Li[Ni0.54Co0.16Mn0.30]O-2 were evaluated and compared to those of conventional Li[Ni0.5Co0.2Mn0.3]O-2 and Li[Ni1/3Co1/3Mn1/3]O-2 materials. It was found that the FCG Li[Ni0.54Co0.16Mn0.30]O-2 demonstrated a higher discharge capacity and a superior lithium intercalation stability compared to Li[Ni0.5Co0.2Mn0.3]O-2 and Li[Ni1/3Co1/3Mn1/3]O-2 over all of the tested voltage ranges. The results of electrochemical impedance spectroscopy and transition-metal dissolution demonstrate that the microstructure of primary particle with rod-shaped morphology plays an important role in reducing metal dissolution, which thereby decreases the charge transfer resistance as a result of stabilization of the host structure.
URI
http://onlinelibrary.wiley.com/doi/10.1002/cssc.201300379/abstracthttp://hdl.handle.net/20.500.11754/47215
ISSN
1864-5631
DOI
10.1002/cssc.201300379
Appears in Collections:
COLLEGE OF ENGINEERING[S](공과대학) > ENERGY ENGINEERING(에너지공학과) > Articles
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