Aerobic oxidation of aldehydes by visible light photocatalysis

Title
Aerobic oxidation of aldehydes by visible light photocatalysis
Author
조은진
Keywords
Photocatalyst; Oxygen; Visible light; Aldehyde; Carboxylic acid
Issue Date
2013-11
Publisher
Elsevier Science B.V., Amsterdam.
Citation
TETRAHEDRON LETTERS, 권: 54, 호: 46, 페이지: 6222-6225
Abstract
An efficient and environmentally benign method for the oxidation of aldehydes to carboxylic acids has been developed. Singlet oxygen, generated by visible light in the presence of a Ru or Ir photocatalyst, reacted with aldehydes to give the corresponding carboxylic acids in excellent yields. The reaction is highly chemo-selective, in which only an aldehyde moiety is reactive even in the presence of other photo-oxidation active sites. This method is an example of an ideal green chemical reaction in the sense that molecular oxygen and visible light are key sources for the transformation. (C) 2013 Elsevier Ltd. All rights reserved
URI
https://www.sciencedirect.com/science/article/pii/S0040403913015505?via%3Dihubhttp://hdl.handle.net/20.500.11754/46316
ISSN
0040-4039
DOI
10.1016/j.tetlet.2013.09.005
Appears in Collections:
GRADUATE SCHOOL[S](대학원) > BIONANOTECHNOLOGY(바이오나노학과) > Articles
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