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(E)-beta-Borylstyrene in the Diels-Alder Reaction with 3,5-Dibromo-2-pyrone for the Syntheses of (+/-)-1-epi-Pancratistatin and (+/-)- Pancratistatin

Title
(E)-beta-Borylstyrene in the Diels-Alder Reaction with 3,5-Dibromo-2-pyrone for the Syntheses of (+/-)-1-epi-Pancratistatin and (+/-)- Pancratistatin
Other Titles
-)-1-epi-Pancratistatin and (+
Author
조천규
Issue Date
2013-11
Publisher
AMER CHEMICAL SOC
Citation
ORGANIC LETTERS, 권: 15, 호: 22, 페이지: 5806-5809
Abstract
New synthetic routes to (+/-)-1-epi-pancratistatin and (+/-)-pancratistatin were devised using (E)-beta-borylstyrene as a dienophile for the key Diels-Alder reaction with 3,5-dibromo-2-pyrone. The boronate in the cycloadduct was oxidized to provide the pivotal C1-hydroxyl group of the titled compounds.
URI
https://pubs.acs.org/doi/10.1021/ol4028623http://hdl.handle.net/20.500.11754/46302
ISSN
1523-7060; 1523-7052
DOI
10.1021/ol4028623
Appears in Collections:
COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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