1,3-Dipolar cycloaddition of 4-platinumisochromenyliums with an olefin and tandem insertion into benzylic C-H bonds

Title
1,3-Dipolar cycloaddition of 4-platinumisochromenyliums with an olefin and tandem insertion into benzylic C-H bonds
Author
오창호
Issue Date
2013-05
Publisher
Royal Society of Chemistry
Citation
Chemical communications : Chem comm, 2013, 49(50), pp.5690 - 5692
Abstract
Isochromenylium-4-ylplatinum(II) species, generated from 1-(2-alkynylphenyl)hex-5-en-1-ones and Pt(II), reacted with a pendant olefin via [3+2] cycloaddition to form tetracyclic Pt-carbene complexes, which underwent C-H insertion with a benzyloxy group at delta or epsilon positions to give highly complex polycycles, which are otherwise hard to access.
URI
http://pubs.rsc.org/en/Content/ArticleLanding/2013/CC/c3cc42525h#!divAbstract
ISSN
1359-7345
DOI
10.1039/c3cc42525h
Appears in Collections:
COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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