Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 조은진 | - |
dc.date.accessioned | 2018-03-05T05:46:39Z | - |
dc.date.available | 2018-03-05T05:46:39Z | - |
dc.date.issued | 2012-04 | - |
dc.identifier.citation | CHEMISTRY-A EUROPEAN JOURNAL, 18, 15, 4495 ~ 4498 | en_US |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://onlinelibrary.wiley.com/doi/10.1002/chem.201103799/abstract | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11754/42485 | - |
dc.description.abstract | Pick a pathway: Upon activation with an electrophilic transition-metal catalyst, a propargylic acetate undergoes competing [1,2]- and [1,3]-acyloxy migration depending on the reaction temperature as well as the substituent pattern around the alkyne. The nature of the catalyst also affects the reaction course. The reactions provided clear evidence for the interconversion between carbenoid and allene intermediates (see scheme). | en_US |
dc.description.sponsorship | This work was supported by the National Resear ch Foundation of Korea(NRF) under Grant NRF-2011-0013118. E.J.C. thanks Prof. Daesung Lee(University of Illinois at Chicago) for the advice and help with this work | en_US |
dc.language.iso | en | en_US |
dc.publisher | WILEY-V C H VERLAG GMBH, BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY | en_US |
dc.subject | acyloxy migration | en_US |
dc.subject | platinum | en_US |
dc.subject | propargylic acetate | en_US |
dc.subject | reaction mechanisms | en_US |
dc.subject | transition-metal catalysis | en_US |
dc.title | Factors Controlling the Equilibrium of Pt-Catalyzed [1,2]- versus [1,3]-Acyloxy Migration | en_US |
dc.type | Article | en_US |
dc.relation.no | 15 | - |
dc.relation.volume | 18 | - |
dc.identifier.doi | 10.1002/chem.201103799 | - |
dc.relation.page | 4495-4498 | - |
dc.relation.journal | CHEMISTRY-A EUROPEAN JOURNAL | - |
dc.contributor.googleauthor | Cho, Eun Jin | - |
dc.contributor.googleauthor | 조은진 | - |
dc.relation.code | 2012201835 | - |
dc.sector.campus | S | - |
dc.sector.daehak | GRADUATE SCHOOL[S] | - |
dc.sector.department | DEPARTMENT OF BIONANOTECHNOLOGY | - |
dc.identifier.pid | echo | - |
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