Stereoselective Palladium-Catalyzed alpha-Arylation of 3-Aryl-1-Indanones: An Asymmetric Synthesis of (+)-Pauciflorol F
- Title
- Stereoselective Palladium-Catalyzed alpha-Arylation of 3-Aryl-1-Indanones: An Asymmetric Synthesis of (+)-Pauciflorol F
- Author
- 신승훈
- Keywords
- CONDENSATION CASCADE REACTION; SUZUKI-MIYAURA; ENANTIOSELECTIVE SYNTHESIS; STILBENE DERIVATIVES; ARYL HALIDES; RESVERATROL; KETONES; ALDEHYDES; NICKEL; ACID
- Issue Date
- 2011-08
- Publisher
- AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
- Citation
- JOURNAL OF ORGANIC CHEMISTRY, 권: 76, 호: 16, 페이지: 6611-6618
- Abstract
- Highly stereoselective, palladium-catalyzed alpha-arylation reactions of 3-aryl-1-indanones with aryl bromides are described. The use of sodium tert-butoxide as a base in this process is required to elevate the efficiencies and stereoselectivities of these reactions. The new methodology was successfully applied to a highly efficient route for the asymmetric synthesis of (+)-pauciflorol F.
- URI
- https://pubs.acs.org/doi/abs/10.1021/jo2009164
- ISSN
- 0022-3263
- DOI
- 10.1021/jo2009164
- Appears in Collections:
- COLLEGE OF NATURAL SCIENCES[S](자연과학대학) > CHEMISTRY(화학과) > Articles
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